Citation: Tian Fei, Zhang Jian, Yang Wulin, Deng Weiping. Progress in Iridium-Catalyzed Asymmetric Allylic Substitution Reactions via Synergetic Catalysis[J]. Chinese Journal of Organic Chemistry, ;2020, 40(10): 3262-3278. doi: 10.6023/cjoc202005008 shu

Progress in Iridium-Catalyzed Asymmetric Allylic Substitution Reactions via Synergetic Catalysis

Tian Fei ^† ,
Zhang Jian ^† ,
Yang Wulin ^, ,
Deng Weiping ^,

School of Pharmacy and Shanghai Key Laboratory of New Drug Design, East China University of Science and Technology, Shanghai 200237

Corresponding author: Yang Wulin, yangwl@ecust.edu.cn Deng Weiping, weiping_deng@ecust.edu.cn
Received Date: 4 May 2020
Revised Date: 23 May 2020
Available Online: 29 May 2020
Fund Project: the Fundamental Research Funds for the Central Universities 222201814048the Shanghai Sailing Program 18YF140560the National Natural Science Foundation of China 21772038the National Natural Science Foundation of China 21901072Project supported by the National Natural Science Foundation of China (Nos. 21772038, 21901072), the Fundamental Research Funds for the Central Universities (No. 222201814048) and the Shanghai Sailing Program (No. 18YF140560)

Figures(38)

Iridium-catalyzed asymmetric allylic substitution reaction has become one of the most important methods for the synthesis of chiral compounds due to its exceptional branched regioselectivity and excellent enantioselectivity. The scope of nucleophiles will be further expanded by synergetic catalysis system of iridium and other catalysts (organocatalysts, other transition metal catalysts). Besides, it is possible to improve the enantioselectivity of the reaction and even realize the stereodivergent synthesis of the products with multiple stereocenters. The progress in the field of catalytic asymmetric allylic substitutions through synergetic iridium and organocatalysis or other transition metal catalysis is summarized. These reactions are classified according to the types of catalysts (aminocatalyst, phase transfer catalyst, Brønsted acid, Lewis base, transition metal). Meanwhile, the mechanism of representative reactions, the existing problems and the prospects in this area are briefly described.
- asymmetric catalysis,
- allylic substitution reaction,
- iridium catalyst,
- synergetic catalysis
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沈阳化工大学材料科学与工程学院沈阳 110142