Citation: Kong Yaolei, Sun Xiaotong, Weng Jianquan. Selectfluor as "Fluorine-Free" Functional Reagent Applied to Organic Synthesis under Transition Metal-Free Conditions[J]. Chinese Journal of Organic Chemistry, ;2020, 40(9): 2641-2657. doi: 10.6023/cjoc202004005 shu

Selectfluor as "Fluorine-Free" Functional Reagent Applied to Organic Synthesis under Transition Metal-Free Conditions

College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014

Corresponding author: Weng Jianquan, jqweng@zjut.edu.cn
Received Date: 2 April 2020
Revised Date: 13 May 2020
Available Online: 11 June 2020
Fund Project: Project supported by the Natural Science Foundation of Zhejiang Province (No. LY17C140003)the Natural Science Foundation of Zhejiang Province LY17C140003

Figures(28)

Selectfluor, a commercial electrophilic fluorination reagent with superior performance, is widely used in fluorination reactions. In recent years, Selectfluor has also been widely applied as "fluorine-free" functional reagent in organic synthesis. Especially the application of Selectfluor/transition metals synergetic catalytic system has made great progress. However, this catalytic system has some disadvantages, such as the use of expensive transition metals and environmental unfriendliness. Therefore, more and more attention has been paid to the application of Selectfluor as "fluorine-free" functional reagent under transition metal-free conditions. In this paper, classified by the type of reactions, the research progress of Selectfluor as a "fluorine-free" functional reagent in organic synthesis under transition metal-free conditions is reviewed, and their future outlook is also discussed.
- Selectfluor,
- "fluorine-free" functional reagent,
- transition metal-free,
- organic synthesis
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沈阳化工大学材料科学与工程学院沈阳 110142