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Citation: Wei Rongbiao, Bao Hongli. Polarity Umpolung Strategy for the Radical Alkylation of Alkenes[J]. Chinese Journal of Organic Chemistry, ;2020, 40(6): 1797-1799. doi: 10.6023/cjoc202000034 shu

Polarity Umpolung Strategy for the Radical Alkylation of Alkenes

Wei Rongbiao ,
Bao Hongli ^,

Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002

Corresponding author: Bao Hongli, hlbao@fjirsm.ac.cn
Available Online: 4 May 2020

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1. [1]
  Luh, T.-Y.; Leung, M.-K.; Wong, K.-T. Chem. Rev. 2000, 100, 3187. doi: 10.1021/cr990272o
2. [2]
  Giese, B.; González-Gómez, J. A.; Witzel, T. Angew. Chem., Int. Ed. 1984, 23, 69. doi: 10.1002/anie.198400691
3. [3]
  Jian, W.; Ge, L.; Jiao, Y.; Qian, B.; Bao, H. Angew. Chem., Int. Ed. 2017, 56, 3650. doi: 10.1002/anie.201612365
4. [4]
  Qian, B.; Chen, S.; Wang, T.; Zhang, X.; Bao, H. J. Am. Chem. Soc. 2017, 139, 13076. doi: 10.1021/jacs.7b06590
5. [5]
  Bunescu, A.; Ha, T. M.; Wang, Q.; Zhu, J. Angew. Chem., Int. Ed. 2017, 56, 10555. doi: 10.1002/anie.201705353
6. [6]
  Bao, X.; Yokoe, T.; Ha, T. M.; Wang, Q.; Zhu, J. Nat. Commun. 2018, 9, 3725. doi: 10.1038/s41467-018-06246-6
7. [7]
  Wu, X.; Zhu, C. Chem. Commun. 2019, 55, 9747. doi: 10.1039/C9CC04785A
8. [8]
  Yu, J.; Wu, Z.; Zhu, C. Angew. Chem., Int. Ed. 2018, 57, 17156. doi: 10.1002/anie.201811346
9. [9]
  Liu, J.; Wu, S.; Yu, J.; Lu, C.; Wu, Z.; Wu, X.; Xue, X. S.; Zhu, C. Angew. Chem., Int. Ed. 2020, 59, 8195. doi: 10.1002/anie.201915837
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