Citation: Hu Yongqin, Huang Danfeng, Wang Kehu, Zhao Zhuanxia, Zhao Fangxia, Xu Weigang, Hu Yulai. Study on Allylation Reactions of Trifluoromethylated Acylhydrazones with Allylsilanes or Allylboronates[J]. Chinese Journal of Organic Chemistry, ;2020, 40(6): 1689-1696. doi: 10.6023/cjoc201912006 shu

Study on Allylation Reactions of Trifluoromethylated Acylhydrazones with Allylsilanes or Allylboronates

College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070

Corresponding author: Huang Danfeng, huangdf@nwnu.edu.cn Hu Yulai, huyl@nwnu.edu.cn
Received Date: 4 December 2019
Revised Date: 17 February 2020
Available Online: 29 February 2020
Fund Project: the National Natural Science Foundation of China 21662030Project supported by the National Natural Science Foundation of China (No. 21662030)

Figures(2)

Allylation reactions of trifluoromethylated acylhydrazones with allyltrimethylsilane or pinacolyl allylboronate were found to proceed smoothly in the presence of Lewis acid to afford a series of trifluoromethylated homoallylic N-acylhydrazines with high yields. The results showed that the activity of pinacolyl allylboronate was higher than that of allyltrimethylsilane in allylation of trifluoromethylated acylhydrazones.
- trifluoromethylated acylhydrazone,
- allyltrimethylsilane,
- pinacolyl allylboronate,
- allylation,
- trifluoromethylated homoallylic N-acylhydrazine
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