Citation: Ouyang Banlai, Zheng Yanxia, Xia Kejian, Xu Xiaoling, Wang Yi. Recent Progress in Transition Metal Catalyzed Sulfonamidation of Aromatic Compounds[J]. Chinese Journal of Organic Chemistry, ;2020, 40(5): 1188-1205. doi: 10.6023/cjoc201910002 shu

Recent Progress in Transition Metal Catalyzed Sulfonamidation of Aromatic Compounds

Department of Chemistry, Nanchang Normal University, Nanchang 330032

Corresponding author: Ouyang Banlai, blouyang@qq.com
Received Date: 5 October 2019
Revised Date: 16 December 2019
Available Online: 3 January 2020
Fund Project: the Open Project Program of Key Laboratory of Functional Small Organic Molecule, Ministry of Education, Jiangxi Normal University KLFS-KF-201721the Science and Technology Project of the Education Department of Jiangxi Province GJJ161235Project supported by the Open Project Program of Key Laboratory of Functional Small Organic Molecule, Ministry of Education, Jiangxi Normal University (No. KLFS-KF-201721) and the Science and Technology Project of the Education Department of Jiangxi Province (No. GJJ161235)

Figures(51)

The N-arylsulfonamide group is an important moiety in medicinal chemistry because of its presence in many useful molecules with potential bioactivities. As a result, the development of synthetic routes to N-arylsulfonamides has been actively investigated. In recent years, the transition metal-catalyzed sulfonamidations of aryl halides, arylboronic acids and C_Ar-H bonds have extensively investigated, providing more efficient and environmentally friendly procedures for the synthesis of N-arylsulfonamides. The recent progress in the transition metal-catalyzed sulfonamidation reactions is reviewed. The aromatic substrates, transition metal-catalysts, ligands, sulfonamidating reagents, mechanisms of the sulfonamidation reactions are mainly discussed. Finally, the future development of them is also prospected.
- N-arylsulfonamides,
- sulfonamidation,
- transition metal-catalyzed,
- C-N bond construction,
- C-H bond activation
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