Citation: Du Linlin, Li Tiesheng. Visible-Light Induced Cyanomethylation of Diaryl Allyl Alcohols to Synthesize δ-Ketonitriles[J]. Chinese Journal of Organic Chemistry, ;2020, 40(1): 140-148. doi: 10.6023/cjoc201905054 shu

Visible-Light Induced Cyanomethylation of Diaryl Allyl Alcohols to Synthesize δ-Ketonitriles

Du Linlin ,
Li Tiesheng ^,

Henan Key Laboratory of Chemical Biology and Organic Chemistry, Key Laboratory of Applied Chemistry of Henan Universities, College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450052

Corresponding author: Li Tiesheng, lts34@zzu.edu.cn
Received Date: 31 May 2019
Revised Date: 24 August 2019
Available Online: 5 January 2019

Figures(3)

A photocatalyzed method for the synthesis of δ-ketonitriles from the reaction of diaryl allyl alcohols with bromoacetonitrile is developed. The result of control experiments indicates that the reaction might proceed via a free radical mechanism and bromoacetonitrile was the source of cyanomethyl radical.
- photocatalyzed,
- diaryl allyl alcohol,
- radical
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