Citation: Luo Feihua. Progress in Transition Metal Catalyzed C-H Functionalization Directed by Carboxyl Group[J]. Chinese Journal of Organic Chemistry, ;2019, 39(11): 3084-3104. doi: 10.6023/cjoc201905027 shu

Progress in Transition Metal Catalyzed C-H Functionalization Directed by Carboxyl Group

Luo Feihua ^,

College of Materials Science and Engineering, Yangtze Normal University, Fuling, Chongqing 408100

Corresponding author: Luo Feihua, 20180011@yznu.edu.cn
Received Date: 13 May 2019
Revised Date: 12 June 2019
Available Online: 9 November 2019
Fund Project: the Scientific and Technological Research Program of Fuling District Commission 2018BBA3039the Introduction of Yangtze Normal University Scientific Research Grants Project 011160011the Scientific and Technological Research Program of Fuling District Commission FLKJProject supported by the Scientific and Technological Research Program of Fuling District Commission (No. FLKJ, 2018BBA3039), and the Introduction of Yangtze Normal University Scientific Research Grants Project (No. 011160011)

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The C-H activation assisted by directing groups is an important measure for selective C-H activation at specific positions, and it is also one of the hot spots in the research field of organic chemistry. As an efficient directing group, carboxylic acid has the advantages of low cost, low toxicity, easy modification and using as traceless directing groups. Recent development on C-H functionalization directed by carboxyl group according to different coupling modes is summarized, and the representative reaction mechanism is briefly described. Existing problems with a brief outlook in this field are also presented.
- catalysis,
- C-H activation,
- carboxylic acid,
- traceless directing group,
- reaction mechanism
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