Citation: Wang Mingfeng, Yu Maodong, Wang Wenshu, Lin Weili, Luo Feixian. Cross-Coupling of C-Si Bond by Using Silyl Reagents[J]. Chinese Journal of Organic Chemistry, ;2019, 39(11): 3145-3153. doi: 10.6023/cjoc201904024 shu

Cross-Coupling of C-Si Bond by Using Silyl Reagents

Wang Mingfeng ^a ,
Yu Maodong ^a ,
Wang Wenshu ^a,c ,
Lin Weili ^a ,
Luo Feixian ^a,b,c,,

a.
College of Life and Environment Science, Minzu University of China, Beijing 100081
b.
MUC Center on Translational Neuroscience, Minzu University of China, Beijing 100081
c.
Experimental Center of Chemistry, Minzu University of China, Beijing 100081

Corresponding author: Luo Feixian, luofeixian@muc.edu.cn
Received Date: 10 April 2019
Revised Date: 28 May 2019
Available Online: 24 November 2019
Fund Project: the National Natural Science Foundation of China 91744206the Promotion Program for Young Teacher in Science and Technology Research of Minzu University of China 2019QNPY60Project supported by the National Natural Science Foundation of China (Nos. 21901263, 91744206), and the Promotion Program for Young Teacher in Science and Technology Research of Minzu University of China (No. 2019QNPY60)the National Natural Science Foundation of China 21901263

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Organosilanes have been widely applied in synthetic chemistry, pharmaceuticals, agrochemicals, and materials due to the special properties. Several synthetic strategies including nucleophilic substitution, hydrosilylation of alkene, and C-H silylation have been developed. In recent years, significant progress has advanced in the cross-coupling of C-Si bond for the synthesis of organosilanes, especially in the break-through of the cross-coupling of C(sp³)-Si bond. It has become one of the hottest issues in synthetic chemistry. The recent progress on the cross-coupling of C-Si bond by using silyl reagents is summarized. The application of silyl reagents in cross-coupling for C-Si bond formation including silyl boranes, organosilyl magnesium, organosilyl zinc, unasymetric disilanes, organosilyl aluminum and organosilyl lithium reagents is mainly discussed.
- silyl reagents,
- cross-coupling,
- transition-metal catalysis,
- organosilanes
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