Citation: Chen Xiaoling, Chen Jingwen, Bao Zongbi, Yang Qiwei, Yang Yiwen, Ren Qilong, Zhang Zhiguo. MIL-101(Cr)-SO₃H Catalyzed Transfer Hydrogenation of 2-Substituted Quinoline Derivatives[J]. Chinese Journal of Organic Chemistry, ;2019, 39(6): 1681-1687. doi: 10.6023/cjoc201902028 shu

MIL-101(Cr)-SO₃H Catalyzed Transfer Hydrogenation of 2-Substituted Quinoline Derivatives

Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027

Corresponding author: Zhang Zhiguo, zhiguo.zhang@zju.edu.cn
Received Date: 25 February 2019
Revised Date: 12 April 2019
Available Online: 6 June 2019
Fund Project: the National Natural Science Foundation of China 21722609Project supported by the National Key R & D Program of China (No. 2016YFA0202900), and the National Natural Science Foundation of China (Nos. 21878266, 21722609)the National Key R & D Program of China 2016YFA0202900the National Natural Science Foundation of China 21878266

Figures(6)

The 2-substituted-1, 2, 3, 4-tetrahydroquinoline skeletons are widely found in natural products and have shown antimalarial, antioxidant as well as other biological activities. In this work, MIL-101(Cr)-SO₃H is an efficient heterogeneous catalyst for the transfer hydrogenation of a series of 2-substituted quinoline derivatives with Hantzsch ester as the hydrogen source. This protocol operates under mild conditions, tolerates a wide range of 2-substituted quinoline derivatives, and the catalyst could be recovered and reused four times without considerable loss of catalytic activities, which provides a new catalytic system for the construction of 2-substituted-1, 2, 3, 4-tetrahydroquinoline derivatives.
- Hantzsch ester,
- heterogeneous catalysis,
- hydrogen transfer,
- MIL-101(Cr)-SO₃H,
- 1, 2, 3, 4-tetrahydroquinolines
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MIL-101(Cr)-SO₃H Catalyzed Transfer Hydrogenation of 2-Substituted Quinoline Derivatives