Citation: Zong Wuzhong, Hu Yulai, Wang Xiaoping, Liu Jiaxin, Huang Danfeng, Wang Kehu. Study on the Chlorination Reaction of Hydrazones by Using of Trichloroisocyanuric Acid as Chloride Source[J]. Chinese Journal of Organic Chemistry, ;2019, 39(5): 1396-1403. doi: 10.6023/cjoc201811039 shu

Study on the Chlorination Reaction of Hydrazones by Using of Trichloroisocyanuric Acid as Chloride Source

College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070

Corresponding author: Hu Yulai, huyl@nwnu.edu.cn
Received Date: 30 November 2018
Revised Date: 17 January 2019
Available Online: 31 May 2019
Fund Project: Project supported by the National Natural Science Foundation of China (No. 21662030)the National Natural Science Foundation of China 21662030

Figures(1)

The chlorination reaction of hydrazones with N-aryltrifluoroacetohydrazones by using trichloroisocyanuric acid as chlorine source was investigated, and a series of N-arylhydrazonyl chlorides and N-aryltrifluoroacetohydrazonyl chlorides were obtained in high yields. This method had advatages of easy operation, short reaction time, mild conditions and the use of stable and cheap chlorine source, which provides an efficiant method for the synthesis of N-arylhydrazonyl chlorides and N-aryltrifluoroacetohydrazonyl chlorides.
- trichloroisocyanuric acid,
- chlorination reaction,
- hydrazonyl chlorides,
- trifluoroacetohydrazonyl chlorides,
- synthesis
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