Citation: He Zhenxiu, Zhou Yongyun, Sun Weiqing, Fan Ruifeng, Shen Guol, Fan Baomin. Asymmetric Ring Opening Reaction of Oxabenzonorbornadienes with Phenols Promoted by Rhodium/Zinc Complexes[J]. Chinese Journal of Organic Chemistry, ;2019, 39(3): 754-760. doi: 10.6023/cjoc201808027 shu

Asymmetric Ring Opening Reaction of Oxabenzonorbornadienes with Phenols Promoted by Rhodium/Zinc Complexes

He Zhenxiu ^a ,
Zhou Yongyun ^a,, ,
Sun Weiqing ^a ,
Fan Ruifeng ^b ,
Shen Guol ^a ,
Fan Baomin ^a,b,,

a.
Yunnan Minzu University-Hong Kong Baptist University Joint Laboratory of Traditional Natural Medicine, Yunnan Minzu University, Kunming 650500
b.
Key Laboratory of Chemistry in Ethnic Medicinal Resources, Yunnan Minzu University, Kunming 650500

Corresponding author: Zhou Yongyun, zhouyongyundf@163.com Fan Baomin, adams.bmf@hotmail.com
Received Date: 23 August 2018
Revised Date: 9 October 2018
Available Online: 11 March 2018
Fund Project: the Applied Basic Research Project of Yunnan Province 2017FA004the National Natural Science Foundation of China 21572198Project supported by the National Natural Science Foundation of China (No. 21572198) and the Applied Basic Research Project of Yunnan Province (No. 2017FA004)

Figures(1)

The complex of[Rh(COD) Cl]₂ and 2R, 4R) -(+) -2, 4-bis(diphenylphosphino) pentane was used as an effective catalyst for the asymmetric ring opening reaction of oxabenzonorbornadienes with various phenols by employing ZnI₂ as the activator. Under the optimized reaction conditions, high enantioselectivities with good yields could be obtained from a wide scope of oxabenzonorbornadienes and phenols.
- rhodium,
- oxabenzonorbornadienes,
- Co-catalysis,
- symmetric ring opening reaction,
- Lewis acid
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