Citation: Niu Jie, Chen Yong, Liu Yu. Construction of Cyclodextrin/Aminoclay-Based Supramolecular Hydrogel and Its I₃^-/I₂ Adsorption Property[J]. Chinese Journal of Organic Chemistry, ;2019, 39(1): 151-156. doi: 10.6023/cjoc201807054 shu

Construction of Cyclodextrin/Aminoclay-Based Supramolecular Hydrogel and Its I₃^-/I₂ Adsorption Property

Niu Jie ^a ,
Chen Yong ^a ,
Liu Yu ^a,b,,

a.
State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071
b.
Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Tianjin 300072

Corresponding author: Liu Yu, yuliu@nankai.edu.cn
Received Date: 29 July 2018
Revised Date: 17 September 2018
Available Online: 26 January 2018
Fund Project: the National Natural Science Foundation of China 21861132001Project supported by the National Natural Science Foundation of China (Nos. 21432004, 21672113, 21772099, 21861132001, 91527301)the National Natural Science Foundation of China 21772099the National Natural Science Foundation of China 21432004the National Natural Science Foundation of China 91527301the National Natural Science Foundation of China 21672113

Figures(4)

Aminoclay (AC), as a kind of layered silicates with positive charges, shows high dispersity in water and has been widely applied in the fabrication of intelligent hybrid hydrogel. Herein, heptakis-[6-deoxy-6-(2-sulfanylethanesulfonic acid)]-β-cyclodextrin (SCD), a kind of negatively charged cyclodextrin, was employed to construct the supramolecular hydrogel with aminoclay through the static electronic interactions, and the resultant SCD-AC hydrogel was fully characterized by means of X-ray powder diffraction (XRD), scanning electronic microscopy (SEM), fourier transform infrared spectroscopy (FT-IR), zeta potential, rheological test, etc. Significantly, the SCD-AC hydrogel can efficiently absorb not only I₃^- ion in aqueous solution but also I₂ molecule in organic solvent, giving a high adsorption capacity up to 90% with 10 min.
- supramolecular hydrogel,
- cyclodextrin,
- aminoclay,
- iodine,
- adsorption
1. [1]
  Lee, K. Y.; Mooney, D. J. Chem. Rev. 2001, 101, 1869. doi: 10.1021/cr000108x
2. [2]
  Park, M.-R.; Seo, B.-B.; Song, S.-C. Biomaterials 2013, 34, 1327. doi: 10.1016/j.biomaterials.2012.10.033
3. [3]
  Peppas, N. A.; Hilt, J. Z.; Khademhosseini, A.; Langer, R. Adv. Mater. 2006, 18, 1345. doi: 10.1002/(ISSN)1521-4095
4. [4]
  Jianyu, L.; Eckhard, W.; Sabine, G.-G.; Michael, S.; Andreas, K.; Christine, H.; Nathalie, A.; Arno, D.; Anne, B.; Brno, T.; Kuno, W.; Mara, F.; Michaela, K.; Alexander, S.; R., F. B.; J., M. D. Adv. Healthcare Mater 2018, 7, 1701393. doi: 10.1002/adhm.v7.9
5. [5]
  Qiu, Y.; Park, K. Adv. Drug Delivery Rev. 2001, 53, 321. doi: 10.1016/S0169-409X(01)00203-4
6. [6]
  Ma, X.-Y.; Shi, L. J.; Zhou, J.; Zhu, J.; Zhong, J.; Wei, R. L. Chin. J. Org. Chem. 2013, 33, 1080(in Chinese).
7. [7]
  Gan, L.; Li, H.; Chen, L.; Xu, L.; Liu, J.; Geng, A.; Mei, C.; Shang, S. Colloid Polym. Sci. 2018, 296, 607. doi: 10.1007/s00396-018-4281-3
8. [8]
  Yuri, N.; Itaru, S.; Yoshimi, S.; Yoshio, N. Chem. Lett. 2007, 36, 1204. doi: 10.1246/cl.2007.1204
9. [9]
  Guo, Y.; Wang, R.; Shang, Y.; Liu, H. RSC Adv. 2018, 8, 8699. doi: 10.1039/C8RA00171E
10. [10]
  Shih, I.-L.; Shen, M.-H.; Van, Y.-T. Bioresour. Technol. 2006, 97, 1148. doi: 10.1016/j.biortech.2004.08.012
11. [11]
  Niu, Y.; Guo, T.; Yuan, X.; Zhao, Y.; Ren, L. Soft Matter 2018, 14, 1227. doi: 10.1039/C7SM02251D
12. [12]
  Lee, K.; Asher, S. A. J. Am. Chem. Soc. 2000, 122, 9534. doi: 10.1021/ja002017n
13. [13]
  Kobayashi, M.; Toguchida, J.; Oka, M. J. Biomed. Mater. Res. 2001, 58, 344. doi: 10.1002/(ISSN)1097-4636
14. [14]
  Hamidi, M.; Azadi, A.; Rafiei, P. Adv. Drug Delivery Rev. 2008, 60, 1638. doi: 10.1016/j.addr.2008.08.002
15. [15]
  Lehr, C.-M.; Bouwstra, J. A.; Schacht, E. H.; Junginger, H. E. Int. J. Pharm. 1992, 78, 43. doi: 10.1016/0378-5173(92)90353-4
16. [16]
  Jeong, B.; Kim, S. W.; Bae, Y. H. Adv. Drug Delivery Rev. 2002, 54, 37. doi: 10.1016/S0169-409X(01)00242-3
17. [17]
  Shi, H.; Cheng, X. B.; Lin, Q.; Yao, H.; Zhang, Y. M.; Wei, T. B. Chin. J. Org. Chem. 2018, 38, 1718(in Chinese).
18. [18]
  Han, Y.-Q.; Zhou, W. J.; Shen, H. M.; Liu, Q. P.; Yu, W. Y.; Ji, H. B.; She, Y. B. Chin. J. Org. Chem. 2016, 36, 248(in Chinese).
19. [19]
  Kay, E. R.; Leigh, D. A.; Zerbetto, F. Angew. Chem., Int. Ed. 2007, 46, 72. doi: 10.1002/(ISSN)1521-3773
20. [20]
  Daniel, M.-C.; Astruc, D. Chem. Rev. 2004, 104, 293. doi: 10.1021/cr030698+
21. [21]
  Yu, J.; Zhang, Y.-M.; Li, P.-Y.; Liu, Y. Chem. Commun. 2017, 53, 3717. doi: 10.1039/C7CC00736A
22. [22]
  Zeng, F.; Zimmerman, S. C. Chem. Rev. 1997, 97, 1681. doi: 10.1021/cr9603892
23. [23]
  Sangeetha, N. M.; Maitra, U. Chem. Soc. Rev. 2005, 34, 821. doi: 10.1039/b417081b
24. [24]
  Wang, C.-H.; Tang, Q.; Xi, Y.-Y.; Yang, M.; Li, T.; Huang, Y.; Tao, Z. Chin. J. Org. Chem. 2018, 38, 1394(in Chinese).
25. [25]
  Zhao, Q.; Li, S. H.; Liu, Y. Prog. Chem. 2018, 30, 673(in Chinese). doi: 10.7536/PC180101
26. [26]
  Wang, X.; Wang, J.; Yang, Y.; Yang, F.; Wu, D. Polym. Chem. 2017, 8, 3901. doi: 10.1039/C7PY00698E
27. [27]
  Zhao, Q.; Chen, Y.; Li, S.-H.; Liu, Y. Chem. Commun. 2018, 54, 200. doi: 10.1039/C7CC08822A
28. [28]
  Li, Z.; Zhang, Y.-M.; Wang, H.-Y.; Li, H.; Liu, Y. Macromolecules 2017, 50, 1141. doi: 10.1021/acs.macromol.6b02459
29. [29]
  Liu, G.; Zhang, Y. M.; Xu, X.; Zhang, L.; Liu, Y. Adv. Opt. Mater. 2017, 5, 1700149. doi: 10.1002/adom.v5.11
30. [30]
  Chen, J.-F.; Liu, X.; Han, B.-B.; Ding, J.-D.; Zhang, Y.-M.; Lin, Q.; Yao, H.; Wei, T.-B. Chin. J. Org. Chem. 2018, 38, 2741(in Chinese).
31. [31]
  Zhao, Q.; Chen, Y.; Liu, Y. Chin. Chem. Lett. 2018, 29, 84. doi: 10.1016/j.cclet.2017.07.024
32. [32]
  Burkett, S. L.; Press, A.; Mann, S. Chem. Mater. 1997, 9, 1071. doi: 10.1021/cm9700615
33. [33]
  Rao, K. V.; Datta, K. K. R.; Eswaramoorthy, M.; George, S. J. Adv. Mater. 2013, 15, 1713.
34. [34]
  Wang, T.; Li, P.; Li, H. ACS Appl. Mater. Interfaces 2014, 6, 12915. doi: 10.1021/am5028555
35. [35]
  Steffen, A.; Thiele, C.; Tietze, S.; Strassnig, C.; K mper, A.; Lengauer, T.; Wenz, G.; Apostolakis, J. Chem.-Eur. J. 2007, 13, 6801. doi: 10.1002/(ISSN)1521-3765
36. [36]
  Wenz, G.; Strassnig, C.; Thiele, C.; Engelke, A.; Morgenstern, B.; Hegetschweiler, K. Chem.-Eur. J. 2008, 14, 7202. doi: 10.1002/chem.v14:24
37. [37]
  Datta, K. K. R.; Achari, A.; Eswaramoorthy, M. J. Mater. Chem. A 2013, 1, 6707. doi: 10.1039/c3ta00100h
38. [38]
  Zeng, M.-H.; Wang, Q.-X.; Tan, Y.-X.; Hu, S.; Zhao, H.-X.; Long, L.-S.; Kurmoo, M. J. Am. Chem. Soc. 2010, 132, 2561. doi: 10.1021/ja908293n
39. [39]
  Liu, Q.-K.; Ma, J.-P.; Dong, Y.-B. Chem. Commun. 2011, 47, 7185. doi: 10.1039/c1cc11402f
40. [40]
  Jie, K.; Zhou, Y.; Li, E.; Li, Z.; Zhao, R.; Huang, F. J. Am. Chem. Soc. 2017, 139, 15320. doi: 10.1021/jacs.7b09850
1. [1]
  Lin Ding , Jinpeng Zhang , Junfeng Li , Daying Liu . Color Catcher: A Marvelous Encounter of Starch and Iodine. University Chemistry, 2024, 39(6): 334-341. doi: 10.3866/PKU.DXHX202311064
2. [2]
  Hongting Yan , Aili Feng , Rongxiu Zhu , Lei Liu , Dongju Zhang . Reexamination of the Iodine-Catalyzed Chlorination Reaction of Chlorobenzene Using Computational Chemistry Methods. University Chemistry, 2025, 40(3): 16-22. doi: 10.12461/PKU.DXHX202403010
3. [3]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
4. [4]
  Hui Wang , Abdelkader Labidi , Menghan Ren , Feroz Shaik , Chuanyi Wang . 微观结构调控的g-C₃N₄在光催化NO转化中的最新进展：吸附/活化位点的关键作用. Acta Physico-Chimica Sinica, 2025, 41(5): 100039-. doi: 10.1016/j.actphy.2024.100039
5. [5]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
6. [6]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
7. [7]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
8. [8]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
9. [9]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
10. [10]
  Jing JIN , Zhuming GUO , Zhiyin XIAO , Xiujuan JIANG , Yi HE , Xiaoming LIU . Tuning the stability and cytotoxicity of fac-[Fe(CO)₃I₃]^- anion by its counter ions: From aminiums to inorganic cations. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 991-1004. doi: 10.11862/CJIC.20230458
11. [11]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
12. [12]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
13. [13]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
14. [14]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
15. [15]
  Hongyun Liu , Jiarun Li , Xinyi Li , Zhe Liu , Jiaxuan Li , Cong Xiao . Course Ideological and Political Design of a Comprehensive Chemistry Experiment: Constructing a Visual Molecular Logic System Based on Intelligent Hydrogel Film Electrodes. University Chemistry, 2024, 39(2): 227-233. doi: 10.3866/PKU.DXHX202309070
16. [16]
  Ruitong Zhang , Zhiqiang Zeng , Xiaoguang Zhang . Improvement of Ethyl Acetate Saponification Reaction and Iodine Clock Reaction Experiments. University Chemistry, 2024, 39(8): 197-203. doi: 10.3866/PKU.DXHX202312004
17. [17]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
18. [18]
  Jin Tong , Shuyan Yu . Crystal Engineering for Supramolecular Chirality. University Chemistry, 2024, 39(3): 86-93. doi: 10.3866/PKU.DXHX202308113
19. [19]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
20. [20]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(1471)
HTML views(291)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Construction of Cyclodextrin/Aminoclay-Based Supramolecular Hydrogel and Its I3-/I2 Adsorption Property

Metrics

通讯作者: 陈斌, bchen63@163.com

Construction of Cyclodextrin/Aminoclay-Based Supramolecular Hydrogel and Its I₃^-/I₂ Adsorption Property