Citation: Li Yuanyuan, Cheng Yuhua, Shan Chunhui, Zhang Jing, Xu Dongdong, Bai Ruopeng, Qu Lingbo, Lan Yu. Recent Advances in Alkaline-Earth-Metal-Catalyzed Hydrofunctionalization Reactions[J]. Chinese Journal of Organic Chemistry, ;2018, 38(8): 1885-1896. doi: 10.6023/cjoc201804031 shu

Recent Advances in Alkaline-Earth-Metal-Catalyzed Hydrofunctionalization Reactions

Li Yuanyuan ^a,b,d ,
Cheng Yuhua ^a ,
Shan Chunhui ^c ,
Zhang Jing ^e ,
Xu Dongdong ^c ,
Bai Ruopeng ^c ,
Qu Lingbo ^d ,
Lan Yu ^c,d,,

a.
College of Biological and Chemical Engineering, Chongqing University of Education, Chongqing 400067
b.
Cooperative Innovation Center of Lipid Resources and Children's Daily Chemicals, Chongqing University of Education, Chongqing 400067
c.
School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 401331
d.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450006
e.
Department of Chemistry and Chemical Engineering, Jining University, Jining 272001

Corresponding author: Lan Yu, lanyu@cqu.edu.cn
Received Date: 16 April 2018
Revised Date: 11 May 2018
Available Online: 17 August 2018
Fund Project: the Project of Science and Technology Collaborative Innovation Platform Construction of Chongqing University of Education 2017XJPT01the Basic and Frontier Research Project of Chongqing Science and Technology Commission cstc2017jcyjAX0371the Scientific Research Foundation of Chongqing University of Education 2017BSRC001the University-level Key Projects of Chongqing University of Education KY201704AProject supported by the Basic and Frontier Research Project of Chongqing Science and Technology Commission (No. cstc2017jcyjAX0371), the Project of Science and Technology Collaborative Innovation Platform Construction of Chongqing University of Education (No. 2017XJPT01), the University-level Key Projects of Chongqing University of Education (No. KY201704A), and the Scientific Research Foundation of Chongqing University of Education (No. 2017BSRC001)

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Alkaline-earth-metal compounds have been widely concerned due to its abundant reserve and the low-cost. In recent years, alkaline-earth-metal catalysis has achieved great progress in dehydrocoupling, hydroboration, hydrophosphination, hydroamination, hydrosilylation reactions experimentally and therotically. These types of reaction and catalytic mechanism, leading to indentify the role of alkaline-earth-metal in hydrogenation and dehydrogenation reaction are summarized. These reactions, in which the metal-hydride act as active species, generally undergo the reaction pathway involving the cleavage and formation of the metal-hydride covalent bond. The reaction features and mechanisms are generally recognized accrossing to the classification and discussion of these reactions, which would provide guidance for further development of alkaline-earth-metal catalysis.
- alkaline-earth-metals catalyst,
- hydrofunctionalization reaction,
- mechanism study,
- recent advance
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