Citation: Wu Yao, Dou Zhengjie, Wu Caimei, Chen Huabao, Zhang Zumin, Wang Xianxiang, Yin Zhongqiong, Song Xu, He Changliang, Yue Guizhou. Application of Mesitylboronic Acid and Its Esters in Coupling Reactions[J]. Chinese Journal of Organic Chemistry, ;2018, 38(11): 2896-2926. doi: 10.6023/cjoc201804027 shu

Application of Mesitylboronic Acid and Its Esters in Coupling Reactions

a.
College of Science, Sichuan Agricultural University, Ya'an 625014
b.
Animal Nutrition Institute, Sichuan Agricultural University, Chengdu 611130
c.
College of Agricultural Sciences, Sichuan Agricultural University, Chengdu 611130
d.
College of Veterinary Medicine, Sichuan Agricultural University, Chengdu 611130

Corresponding author: Yue Guizhou, yueguizhou@sicau.edu.cn
Received Date: 15 April 2018
Revised Date: 19 June 2018
Available Online: 5 November 2018
Fund Project: Project supported by the Science & Technology Department of Sichuan Province (No. 2012JY0118) and the Sichuan Agricultural Universitythe Science & Technology Department of Sichuan Province 2012JY0118

Figures(31)

Organic boronic reagents have played a critical role in the field of organic synthesis, especially Suzuki coupling, since they were founded. In return, all kinds of transition metal (Pd, Ni, Rh, Au etc.)-catalyzed coupling reactions have given a big push for the development and application of organic boronic reagents. 2, 4, 6-Mesitylboronic acid was used widely in various coupling reactions, including Suzuiki reaction, aromatic C-H activation, oxidative Heck reaction, carbonlation, decarboxylation, photoredox reaction and other C-X (C-N, C-S, C-Se) bonding reaction, which was used to synthesize functional materials, ligands and drug molecules. This paper includes two aspects:(1) reviewing the application of mesityl boronic acid and its ester in coupling reaction, and (2) making our points and respecting for this field.
- mesitylboronic acid,
- coupling reaction,
- C-H activiation,
- synthesis
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