Citation: Li Gang, Chen Ye, Xia Jibao. Progress on Transition-Metal-Catalyzed Cross-Coupling Reactions of Ammonium Salts via C-N Bond Cleavage[J]. Chinese Journal of Organic Chemistry, ;2018, 38(8): 1949-1962. doi: 10.6023/cjoc201803013 shu

Progress on Transition-Metal-Catalyzed Cross-Coupling Reactions of Ammonium Salts via C-N Bond Cleavage

Li Gang ^a,b ,
Chen Ye ^a,, ,
Xia Jibao ^b,,

a.
School Chemistry of Chemical Engineering, Guizhou University, Guiyang 550025
b.
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics(LICP), Chinese Academy of Sciences, Lanzhou 730000

Corresponding author: Chen Ye, ychen19@gzu.edu.cn Xia Jibao, jibaoxia@licp.cas.cn
Received Date: 12 March 2018
Revised Date: 8 April 2018
Available Online: 27 August 2018
Fund Project: Project supported by the National Natural Science Foundation of China (Nos. 21702212, 21772208, 21602230) and the Natural Science Foundation of Jiangsu Province (No. BK20161260)the National Natural Science Foundation of China 21602230the National Natural Science Foundation of China 21702212the Natural Science Foundation of Jiangsu Province BK20161260the National Natural Science Foundation of China 21772208

Figures(5)

Amines containing carbon-nitrogen (C-N) bonds are widely distributed in natural products, drug molecules and functional materials.C-N bonds are one of the most abundant and inert bonds in organic molecules.Selective cleavage of C-N bonds to construct carbon-carbon (C-C) and carbon-heteroatom (C-X) bonds represents a new synthetic method in organic synthesis.It is difficult for the direct cleavage of C-N bond.Ammonium salts are a series of stable compounds easily obtained from amines.The recent progress of transition-metal-catalyzed cross-coupling reactions via C-N bond cleavage using ammonium salts as starting materials is summerized.
- transition-metal-catalysis,
- ammonium salt,
- cross-coupling reaction,
- C-N bond cleavage
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