Citation: Hou Yadong, Dong Xiuzhi, Yang Chao, Hui Yonghai, Xie Zhengfeng. MCM-41 Immobilized H₃PW₁₂O₄₀ Catalyzed the Addition-Elimination Reaction of Imine with Malonitrile in Water[J]. Chinese Journal of Organic Chemistry, ;2018, 38(7): 1749-1754. doi: 10.6023/cjoc201802006 shu

MCM-41 Immobilized H₃PW₁₂O₄₀ Catalyzed the Addition-Elimination Reaction of Imine with Malonitrile in Water

Hou Yadong ^a ,
Dong Xiuzhi ^a ,
Yang Chao ^a,, ,
Hui Yonghai ^a,b,, ,
Xie Zhengfeng ^a,c

a.
Key Laboratory of Oil & Gas Fine Chemicals, Ministry of Education & Xinjiang Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046
b.
School of Chemistry and Chemistry Engineering, Lingnan Normal University, Zhanjiang 524048
c.
School of Chemistry and Chemistry Engineering, Southwest Petroleum University, Chengdu 610500

Corresponding author: Yang Chao, jerryyang1924@163.com Hui Yonghai, hyhai97@126.com
Received Date: 3 February 2018
Revised Date: 7 March 2018
Available Online: 29 July 2018
Fund Project: Project supported by the National Natural Science Foundation of China (Nos. 21362036, 51564045)the National Natural Science Foundation of China 51564045the National Natural Science Foundation of China 21362036

Figures(3)

A convenient and excellent yield procedure for the preparation of benzylidenemalononitrile by addition-elimination reaction of imine with malonitrile in the presence of immobilized H₃PW₁₂O₄₀ as heterogeneous catalyst in water is described, and a variety of the corresponding products were obtained in high yield (up to 99%). The approach was characterized by simple operation, environment friendly, excellent yields and the catalyst was found to exhibit better recyclability. It provides a new method for the carbon-carbon bond formation in organic synthesis.
- MCM-41,
- phosphoric acid,
- addition-elimination reaction,
- heterogeneous catalyst
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MCM-41 Immobilized H₃PW₁₂O₄₀ Catalyzed the Addition-Elimination Reaction of Imine with Malonitrile in Water