Citation: Hou Wentao, Jia Xiaodong. Recent Progress in Radical Cation Salts Promoted Chemical Transformations[J]. Chinese Journal of Organic Chemistry, ;2018, 38(5): 999-1008. doi: 10.6023/cjoc201711037 shu

Recent Progress in Radical Cation Salts Promoted Chemical Transformations

Hou Wentao ^a ,
Jia Xiaodong ^a,b,,

a.
College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070
b.
School of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002

Corresponding author: Jia Xiaodong, jiaxd1975@163.com
Received Date: 21 November 2017
Revised Date: 25 December 2017
Available Online: 3 May 2018
Fund Project: the National Natural Science Foundation of China 1362030the National Natural Science Foundation of China 21562038Project supported by the National Natural Science Foundation of China (Nos. 1362030, 21562038)

Figures(19)

The first radical cation salt (RCS) was prepared more than 100 years ago, and with the recent renaissance of radical chemistry, the RCS promoted organic transformations attrack extensively attention. In early research, RCS was mainly used to initiate single electron oxidation reactions, such as cycloaddition, fragmentation, rearrangement and so on. Recently, RCS was used to induce the aerobic oxidation of C—H bond, and achieved a series of direct functionalization of C—H bond. In this review, prominent examples from the recent literatures are organized on the basis of the different reactions enabled by RCS catalysis.
- radical cation salt,
- single electron oxidation,
- C—H activation,
- cycloaddition
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