Citation: Huang Qing, Qu Wenjuan, Chen Jie, Lin Qi, Yao Hong, Zhang Youming, Wei Taibao. A Reaction Type Colorimetric and Fluorescence Chemosensor Based on Coumarin Derivatives Design for Detecting Cyanide Ion and Its Application[J]. Chinese Journal of Organic Chemistry, ;2018, 38(3): 629-635. doi: 10.6023/cjoc201709040 shu

A Reaction Type Colorimetric and Fluorescence Chemosensor Based on Coumarin Derivatives Design for Detecting Cyanide Ion and Its Application

Huang Qing ^a,b ,
Qu Wenjuan ^a ,
Chen Jie ^c ,
Lin Qi ^a ,
Yao Hong ^a ,
Zhang Youming ^a ,
Wei Taibao ^a,,

a.
Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education; Key Laboratory of Polymer Materials of Gansu Province; College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070
b.
School of Pharmacy, Ningxia Medical University, Yinchuan 750006
c.
Lanzhou City University, Lanzhou 730070

Corresponding author: Wei Taibao, weitaibao@126.com
Received Date: 25 September 2017
Revised Date: 31 October 2017
Available Online: 17 March 2017
Fund Project: the National Natural Science Foundation of China 21661028the National Natural Science Foundation of China 21262032the National Natural Science Foundation of China 21662031the National Natural Science Foundation of China 21574104Project supported by the National Natural Science Foundation of China (Nos. 21662031, 21661028, 21574104, 21262032)

Figures(9)

A novel CN^- chemosensor based N-4-pyridylcoumarin-3-carboxamide derivative Q1 was designed and synthesized. The recognition performance of sensor Q1 for ten different anions was studied by UV and fluorescence spectroscopy. When anions such as CN^-, F^-, Cl^-, Br^-, I^-, AcO^-, H₂PO₄^-, HSO₄^-, ClO₄^- and SCN^- were added to the mixed solution (DMSO/H₂O, V:V=9:1), addition of CN^- could increase the absorption peak of Q1 at 304 nm, and the corresponding fluorescence produced a strong emission peak at 431 nm. Q1 solution with CN^- emitted strong blue fluorescent that can be easily observed by naked eyes. The color changed (from colorless to faint yellow) and the "Turn-On" fluorescence behavior suggested that Q1 could detect CN^- by dual-channel. Happily, the fluorescent limit of detection (LOD) is 1.44×10^-8 mol/L, was lower than the specified content by World Health Organization (WHO) in drinking water. Based on all the experimental facts, we speculated that the possible identification mechanism was that the addition reaction took place between Q1 and CN^-, and it can also be confirmed by density functional theory (DFT). This result can be applied to the detection of CN^- in cherry kernel.
- coumarin derivatives,
- dual-channel,
- cyanide ions,
- food sample application
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