Citation: Qiu Guo, Wang Xincheng, Huang Chongpin, Zhang Pu, Li Yingxia, Chen Biaohua. Synthesis of 5-Hydroxymethylfurfural from Sucrose Catalyzed by Phosphotungstate[J]. Chinese Journal of Organic Chemistry, ;2018, 38(4): 940-948. doi: 10.6023/cjoc201709007 shu

Synthesis of 5-Hydroxymethylfurfural from Sucrose Catalyzed by Phosphotungstate

a.
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029
b.
Beijing Key Laboratory of Fuels Cleaning and Advanced Catalytic Emission Reduction Technology, Beijing Institute of Petrochemical Technology, Beijing 102617

Corresponding author: Huang Chongpin, huangcp@mail.buct.edu.cn
Received Date: 5 September 2017
Revised Date: 8 November 2017
Available Online: 21 April 2017
Fund Project: the National Natural Science Foundation of China 21476021Project supported by the National Natural Science Foundation of China (No. 21476021)

Figures(16)

5-Hydroxymethylfurfural (5-HMF) is one of the most important biomass-derived platform compounds and can be used to produce various chemicals. The synthesis of 5-hydroxymethylfurfural (5-HMF) from sucrose catalyzed by a variety of phosphotungstate (Nb_0.6PW₁₂O₄₀, Sn_0.75PW₁₂O₄₀, CrPW₁₂O₄₀, CePW₁₂O₄₀) has been studied, and the catalysts are characterized by FTIR, XRD, UV-Vis, TGA, NH₃-TPD and NMR. The optimum yield of 5-HMF reached 62.54% with 99.3% conversion of sucrose, using Nb_0.6PW₁₂O₄₀ in dimethyl sulfoxide (DMSO) at 80℃ under 0.1 MPa of N₂ with reaction time of 90 min. Moreover, Nb_0.6PW₁₂O₄₀ could be reused five times without loss of activity, and the reaction mechanism was proposed. This study has reference significance for carbohydrate conversion to 5-HMF .
- 5-hydroxymethylfurfural,
- sucrose,
- phosphotungstate
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