Citation: Liu Shuang, Li Yuming, Wang Dian, Wei Rong, Miao Zhiwei. Research Progress of Asymmetric Synthesis of Optically Active P-Stereogenic Organophosphoryl Compounds by Chiral Induction[J]. Chinese Journal of Organic Chemistry, ;2018, 38(2): 341-349. doi: 10.6023/cjoc201708040 shu

Research Progress of Asymmetric Synthesis of Optically Active P-Stereogenic Organophosphoryl Compounds by Chiral Induction

Liu Shuang ^a ,
Li Yuming ^a ,
Wang Dian ^a ,
Wei Rong ^a ,
Miao Zhiwei ^a,b,,

a.
State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071
b.
Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology Ministry of Education, Tsinghua. University, Beijing 100084

Corresponding author: Miao Zhiwei, miaozhiwei@nankai.edu.cn
Received Date: 20 August 2017
Revised Date: 24 September 2017
Available Online: 16 February 2017
Fund Project: Project supported by the National Key Research and Development Program of China (No. 2016YFD0201200)the National Key Research and Development Program of China 2016YFD0201200

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Organo-phosphorus chemistry is an important branch of organic chemistry and life science research. P-Stereogenic organophosphorus compounds have attracted great interest due to their potential applications in the fields of pharmaceutical chemistry, agrochemistry, material science and as ligands for asymmetric catalysis. The preparation of enantiomerically enriched phosphorus compounds with P-stereogenic centers using natural chiral compounds as chiral auxiliary has received considerable attention. The recent development of the asymmetric synthesis of P-stereogenic organophosphoryl compounds employing menthol, sparteine, ephedrine, and carbohydrates as chiral auxiliary is summarized.
- P-stereogenic organophosphorus compound,
- chiral induction,
- asymmetric synthesis
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