Citation: Gong Baoxiang, Yan Long, Chen Mengyuan, Deng Jin, Fu Yao. Preparation of D-Sorbitol by Catalytic Hydrogenation of D-Glucose with Semi Sandwich Iridium Catalyst[J]. Chinese Journal of Organic Chemistry, ;2017, 37(12): 3170-3176. doi: 10.6023/cjoc201708001 shu

Preparation of D-Sorbitol by Catalytic Hydrogenation of D-Glucose with Semi Sandwich Iridium Catalyst

Anhui Province Key Laboratory of Biomass Clean Energy, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026

Corresponding author: Deng Jin, dengjin@ustc.edu.cn Fu Yao, fuyao@ustc.edu.cn
Received Date: 1 August 2017
Revised Date: 31 August 2017
Available Online: 15 December 2017
Fund Project: the Science Foundation of the Chinese Academy of Sciences XDB20000000the National Natural Science Foundation of China 21325208the Science Foundation of the Chinese Academy of Sciences YZ201563the National Natural Science Foundation of China 21402181the Fundamental Research Funds for the Central Universities, the Program for Changjiang Scholars and Innovative Research Team in University of the Ministry of Education of China, the Key Technologies R&D Programme of Anhui Province 1604a0702027Project supported by the National Natural Science Foundation of China (Nos. 21572212, 21402181, 21325208), the Science Foundation of the Chinese Academy of Sciences (Nos. XDB20000000, YZ201563), the Fundamental Research Funds for the Central Universities, the Program for Changjiang Scholars and Innovative Research Team in University of the Ministry of Education of China, the Key Technologies R&D Programme of Anhui Province (No. 1604a0702027)the National Natural Science Foundation of China 21572212

Figures(3)

[Cp^*Ir-(di-OH-bpy)(OH₂)] [SO₄] (di-OH-bpy=4, 4'-dihydroxyl-2, 2'-bipyridine) exhibited high catalytic performance during the hydrogenation of D-glucose to D-sorbitol. Using formic acid as hydrogen source led to an unsatisfactory D-sorbitol selectivity. The ring-opening hydrogenation of glucose was efficiently achieved by hydrogen. Under optimal conditions, D-sorbitol could be obtained in 96% yield. The effect of different ligands in iridium catalyst on hydrogenation was also investigated. A speculated mechanism was proposed to illustrate the detailed process of D-glucose hydrogenation to produce sorbitol. The catalytic system has the merits of relatively mild reaction conditions and high product selectivity, which provides an effective method for the catalytic hydrogenation of other biomass-based platform chemicals.
- glucose,
- sorbitol,
- Cp^*Ir,
- homogeneous hydrogenation,
- bipyridine ligand
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