Citation: Wang Ligeng, Chen Lujun, Zhang Hualong, Yu Qin. Selective Oxidative Bromination of Anilines Using Potassium Bromide and ZnAl-BrO₃^--LDHs[J]. Chinese Journal of Organic Chemistry, ;2017, 37(12): 3186-3190. doi: 10.6023/cjoc201705017 shu

Selective Oxidative Bromination of Anilines Using Potassium Bromide and ZnAl-BrO₃^--LDHs

College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014

Corresponding author: Wang Ligeng, wanglg@zjut.edu.cn
Received Date: 11 May 2017
Revised Date: 7 July 2017
Available Online: 8 December 2017

Figures(2)

The oxidative bromination of anilines was realized with ZnAl-BrO₃^--LDHs/KBr as the bromine source at ambient temperature in acidic medium (AcOH/H₂O). High yields of monobrominated or polybrominated anilines were achieved for a wide range of anilines. Both the substrate structure and the reaction conditions will significantly influence the reaction selectivity. The use of inexpensive reagents, environmentally benign and operationally simple process, and excellent yields make it a good alternative to the synthesis of bromoanilines.
- anilines,
- halogenation,
- selectivity,
- aromatic substitution
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Selective Oxidative Bromination of Anilines Using Potassium Bromide and ZnAl-BrO3--LDHs

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通讯作者: 陈斌, bchen63@163.com

Selective Oxidative Bromination of Anilines Using Potassium Bromide and ZnAl-BrO₃^--LDHs