Citation: Deng Yingying, Yang Wen, Yang Xin, Yang Dingqiao. Progress in Iridium-Catalyzed Asymmetric Allylic Substitution Reactions with Allylic Esters[J]. Chinese Journal of Organic Chemistry, ;2017, 37(12): 3039-3059. doi: 10.6023/cjoc201704034 shu

Progress in Iridium-Catalyzed Asymmetric Allylic Substitution Reactions with Allylic Esters

Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, School of Chemistry and Environment, South China Normal University, Guangzhou 510006

Corresponding author: Yang Dingqiao, yangdq@scnu.edu.cn
Received Date: 19 April 2017
Revised Date: 21 June 2017
Available Online: 11 December 2017
Fund Project: the Natural Science Foundation of Guangdong Province S2013020013091the Science and Technology Plan Projects of Guangzhou Cit 201510010054the National Natural Science Foundation of China 21172081Project supported by the National Natural Science Foundation of China (Nos. 21172081, 21372090), the Natural Science Foundation of Guangdong Province (No. S2013020013091) and the Science and Technology Plan Projects of Guangzhou City (No. 201510010054)the National Natural Science Foundation of China 21372090

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Iridium-catalyzed asymmetric allylic substitution reaction is one of the most important methods for the synthesis of chiral compounds. The recent research progress in iridium-catalyzed asymmetric allylic substitution reactions of allylic ester and its derivatives is reviewed with focus on the influences of the iridium catalysts, the substrate structures of allylic ester and its derivatives, the type of nucleophiles, the effects of solvents and additives on asymmetric substitution reaction. Moreover, the possible mechanisms are also discussed in this review.
- iridium catalyst,
- allylic esters,
- asymmetric allylic substitution,
- nucleophile,
- recent research progress
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