Citation: Zou Hao, Wang Xueding, Yang Weiqing, Zhang Yuanyuan, Chen Hua, Wang Yuliang, Ma Menglin, Du Quan. Study of the Friedel-Crafts Reaction of Cyanuric Chloride with Low-Boiling Aromatic Ring[J]. Chinese Journal of Organic Chemistry, ;2017, 37(10): 2697-2704. doi: 10.6023/cjoc201704027 shu

Study of the Friedel-Crafts Reaction of Cyanuric Chloride with Low-Boiling Aromatic Ring

a.
Key Laboratory of Advanced Scientific Computation of Sichuan Province, School of Science, Xihua University, Chengdu 610039
b.
Key Laboratory of Green Chemistry and Technology of Ministry of Education, Faculty of Chemistry, Sichuan University, Chengdu 610064

Corresponding author: Ma Menglin, mmlchem@163.com
Received Date: 17 April 2017
Revised Date: 22 May 2017
Available Online: 16 October 2017
Fund Project: Project supported by the Scientific Research Foundation of the Education Department of Sichuan Province (No. 12ZB128) and the Key Research Fund Program of Xihua University (No. Z1123328)the Key Research Fund Program of Xihua University Z1123328the Scientific Research Foundation of the Education Department of Sichuan Province 12ZB128

Figures(6)

The cyanuric chloride and benzene Friedel-Crafts arylation using Lewis acid catalyst in high pressure autoclave was studied in this manuscript. The aim compounds 2, 4-dichloro-6-phenyl-1, 3, 5-triazine and 2, 4, 6-triphenyl-1, 3, 5-triazine could be got with high selectivity and yields by varying reaction temperature, substrate and catalyst amount, which application was expecting and promising. The transition state was obtained by quantum calculation density functional theory (DFT) method using Gaussian software, and the experimental results and mechanism of this reaction were discussed from the point of dynamics and thermo-dynamics.
- cyanuric chloride,
- aromatic ring,
- friedel-crafts arylation reaction,
- autoclave
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沈阳化工大学材料科学与工程学院沈阳 110142