Citation: Lu Zhengyu, Chen Jiangxi, Xia Haiping. Synthesis of Olefinic Carbolong Complexes[J]. Chinese Journal of Organic Chemistry, ;2017, 37(5): 1181-1188. doi: 10.6023/cjoc201703003 shu

Synthesis of Olefinic Carbolong Complexes

a.
College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005
b.
College of Material, Xiamen University, Xiamen 361005

Corresponding author: Xia Haiping, hpxia@xmu.edu.cn
Received Date: 1 March 2017
Revised Date: 17 March 2017

Fund Project: by the National Natural Science Foundation of China 21332002by the National Natural Science Foundation of China 21490573by the National Natural Science Foundation of China 21472156

Figures(6)

Carbolong complexes are a new type of metalla-aromatic compounds with novel skeleton and interesting properties, which could be used as potential interesting materials. However, most of them do not have reactive organic functional groups, which hinder their applications as functional materials via chemical modifications. Olefinic group is a reactive functional group that can be used for polymerization or click reaction and so on. In this work, the synthesis of carbolong complexes attached an olefinic group, which could be used to prepare carbolong-containing materials, is reported based on their reactivity.
- carbolong,
- metallapentalyne,
- metallapentalene,
- olefinic,
- osmium
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