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Citation: Qi Haitang, Song Guanglin, Quan Zhengjun, Wang Xicun. CuSO4·5H2O/NaAsc-Catalyzed Sonogashira Coupling Reaction of Aryl Iodides and Terminal Alkynes[J]. Chinese Journal of Organic Chemistry, ;2017, 37(7): 1855-1859. doi: 10.6023/cjoc201701013 shu

CuSO4·5H2O/NaAsc-Catalyzed Sonogashira Coupling Reaction of Aryl Iodides and Terminal Alkynes

  • College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070

  • Corresponding author: Quan Zhengjun, quanzhengjun@hotmail.com Wang Xicun, wangxicun@nwnu.edu.cn
  • Received Date: 5 January 2017
    Revised Date: 22 February 2017
    Available Online: 14 July 2017

    Fund Project: Project supported by the National Natural Science Foundation of China (Nos. 21362032, 21362031)the National Natural Science Foundation of China 21362032the National Natural Science Foundation of China 21362031

Figures(1)

  • In this paper, the homogeneous catalytic system of CuSO4·5H2O/NaAsc was used to realize the Sonogashira reaction of aryl iodides and terminal alkynes. This catalytic system replaces the general catalytic system of Pd/Cu-bound phosphorus ligand, which has the advantages of cheap catalyst, simple post-treatment, reaction under homogeneous conditions, and meets the requirements of green chemistry.
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