Citation: Hou Shuhua, Wang Siqi, Qu Zhongguo, Zhong Keli, Bian Yanjiang, Tang Lijun. A Fluorescence Enhancement Probe for Trivalent Ions: Preparation and Property[J]. Chinese Journal of Organic Chemistry, ;2017, 37(3): 726-730. doi: 10.6023/cjoc201612004 shu

A Fluorescence Enhancement Probe for Trivalent Ions: Preparation and Property

Department of Chemistry, Bohai University, Jinzhou 121013

Corresponding author: Tang Lijun, bhutang@126.com
Received Date: 2 December 2016
Revised Date: 24 January 2017

Fund Project: the Program for Liaoning Excellent Talents in University LR2015001

Figures(7)

A novel rhodamine-based probe L was synthesized and characterized. The results showed that probe L acted as a fluorescent enhancement probe for Cr³⁺, Fe³⁺ and Al³⁺ recognition in CH₃OH/H₂O (V:V=8:2, c(Tris)=10 mmol/L, pH=7.2). L is highly selective to trivalent ions Cr³⁺, Fe³⁺ and Al³⁺ over other monovalent or divalent ions. Detection limits of probe L for Cr³⁺, Fe³⁺ and Al³⁺ are 2.1×10^-4, 2.3×10^-4 and 4.4×10^-4 mol/L, respectively, which make it have potentially application value in Cr³⁺, Fe³⁺ and Al³⁺ detection in various water samples.
- rhodamine,
- trivalent ions,
- fluorescence enhancement
1. [1]
  (a) Singh, A. K.; Gupta, V.; Gupta, B. Anal. Chim. Acta2007, 585, 171.
  (b) Vincent J B. Nutr. Rev. 2000, 58(3):67.
2. [2]
  (a) Pithadia, A. S.; Lim, M. H. Curr. Opin. Chem. Biol.2012, 16, 67.
  (b) Weizman, H.; Ardon, O.; Mester, B.; Libman, J.; Dwir, O.; Hadar, Y.; Chen, Y.; Shanzer, A. J. Am. Chem. Soc.1996, 118, 12368.
  (c) Touati, D. Arch. Biochem. Biophy.2000, 373, 1.
3. [3]
  (a) Perl, D. P.; Gajdusek, D. C.; Garruto, R. M.; Yanagihara, R. T.; Gibbs, C. J. Science1982, 217, 1053.
  (b) Crapper, D.; Krishnan, S.; Dalton, A. Science1973, 180, 511.
4. [4]
  (a) Ta, C.; Reith, F.; Brugger, J.; Pring, A.; Lenehan, C. E. Environ. Sci. Technol. 2014, 48, 5737.
  (b) Armelao, L.; Bettinelli, M.; Rizzi, G. A.; Russo, U. J. Mater. Chem. 1991, 1, 805.
  (c) Peruchi, L. C.; Nunes, L. C.; Arantes de Carvalho, G. G.; Bueno Guerra, M. B.; de Almeida, E.; Rufini, I. A.; Santos, D., Jr.; Krug, F. J. Spectrochim. Acta B 2014, 100, 129.
5. [5]
  Mao, J.; Wang, L.; Dou, W.; Tang, X.; Yan, Y.; Liu, W. Org. Lett. 2007, 9, 4567. doi: 10.1021/ol7020687
6. [6]
  (a) Azadbakht, R.; Vaisi, H.; Mohamadvand, H.; Khanabadi, J. Spectrochim. Acta A2015, 145, 575.
  (b) Lv, Y.; Zhu, L.; Liu, H.; Wu, Y.; Chen, Z.; Fu, H.; Tian, Z. Anal. Chim. Acta2014, 839, 74.
  (c) Zhan, S.; Xu, H.; Zhang, D.; Xia, B.; Zhan, X.; Wang, L.; Lv, J.; Zhou, P. Biosens. Bioelectron.2015, 72, 95.
  (d) Maiti, S.; Aydin, Z.; Zhang, Y.; Guo, M. Dalton Trans.2015, 44, 8942.
  (e) Wang, M.; Wang, F.; Wang, Y.; Zhang, W.; Chen, X. Dyes Pigm.2015, 120, 307.
  (f) Prabhu, J.; Velmurugan, K.; Nandhakumar, R. J. Anal. Chem.2015, 70, 943.
  (g) Antony, E. J.; Raj, M.; Paulpandi, R. Q.; Paulraj, M. S.; Enoch, I. V. M. V. J. Fluoresc.2015, 25, 1031.
  (h) Geng, T.-M.; Wu, D.-Y.; Huang, W.; Huang, R.-Y.; Wu, G.-H. J. Polym. Res.2014, 21, 354.
  (i) Xu, Z.; Baek, K.-H.; Kim, H. N.; Cui, J.; Qian, X.; Spring, D. R.; Shin, I.; Yoon, J. J. Am. Chem. Soc.2009, 132, 601.
7. [7]
  (a) Chereddy, N. R.; Nagaraju, P.; Raju, M. V.; Krishnaswamy, V. R.; Korrapati, P. S.; Bangal, P. R.; Rao, V. J. Biosens. Bioelectron.2015, 68, 749.
  (b) Hou, S. H.; Qu, Z. G.; Zhong, K. H.; Bian, Y. J.; Tang, L. J. Tetrahedron Lett.2016, 57, 2616.
8. [8]
  Hou, S. H.; Qu, Z. G.; Zhong, K. H.; Bian, Y. J.; Tang, L. J. Chin. J. Org. Chem. 2016, 36, 768 (in Chinese). doi: 10.6023/cjoc201512041
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