Citation: Wang Guokai, Sun Yunpeng, Wang Zheng, Zhang Nan, Wang Gang, Zhou Zhongyu, Liu Jinsong. Two New Flavonoids from Kalimeris integrifolia[J]. Chinese Journal of Organic Chemistry, ;2017, 37(4): 1016-1019. doi: 10.6023/cjoc201611021 shu

Two New Flavonoids from Kalimeris integrifolia

Wang Guokai ^a ,
Sun Yunpeng ^a ,
Wang Zheng ^a ,
Zhang Nan ^a ,
Wang Gang ^a,*,, ,
Zhou Zhongyu ^b ,
Liu Jinsong ^a,*,,

a.
Anhui Key Laboratory for mordern Chinese Materia Medica, School of Pharmacy, Anhui University of Chinese Medicine, Hefei 230012
b.
Guangdong Provincial Key Laboratory of Applied Botany, South China Botanical Garden, Chinese Academy of Sciences, Guangzhou 510650

Corresponding author: Wang Gang, jinsongliu108@sina.com Liu Jinsong, kunhong_8@163.com
Received Date: 18 November 2016
Revised Date: 13 December 2016

Fund Project: the Guangdong Provincial Key Laboratory of Applied Botany, South China Botanical Garden, CAS AB2015001the National Natural Science Foundation of China 81303220the Natural Sciences Foundation of Anhui Province 11040606M220

Figures(2)

Investigation on Kalimeris integrifolia resulted in two compounds by means of various chromatographic techniques (silica gel, Sephadex LH-20, RP-LC and Pre-HPLC). Their structures were determined as 5, 8-dihydroxy-2-(3-hydroxy-4, 5-dimethoxyphenyl)-6, 7-dimethoxy-4H-chromen-4-one (1) and 5-hydroxy-6, 7-dimethoxy-2-(4-methoxyphenyl)-4-oxo-4H-chromen-8-yl 2-methylbutanoate (2) on the basis of extensive spectroscopic analyses including MS, IR, UV, 1D-and 2D-NMR. Among them, compounds 1 and 2 are two new flavonoids, named as kalinturflavone A (1) and kalinturflavone B (2).
- Kalimeris integrifolia,
- Asteraceae,
- chemical constituent,
- flavonoids
1. [1]
  Chinese Flora Editorial Board of Chinese Academy of Sciences Flora of China, Vol. 74, Science Press, Beijing, 1985 (in Chinese).
2. [2]
  Chinese Herbal Editorial Board Chinese Herbal, Shanghai Science and Technology Press, Shanghai, 1999 (in Chinese).
3. [3]
  Ji, P.; Wang, G. K.; , Liu, J. S.; Luo, Z. H.; Liu, J. K.; Wang, G. Nat. Prod. Res. Dev. 2014, 26, 212 (in Chinese).
4. [4]
  Zhong, W. W.; Liu, J. S.; Zhang, C. E.; Chen A. M.; Xu, Y. S.; Wang G. Guihaia 2012, 32, 261 (in Chinese). doi: 10.3969/j.issn.1000-3142.2012.02.023
5. [5]
  Wang, G. K.; Liu, J. S.; Zhang, C. E.; Wang, Z.; Cai, B. X.; Wang, G. Chin. Med. Mater. 2015, 38, 82 (in Chinese).
6. [6]
  Liu, J. S.; Wang G.; Wang, G. K.; Yu, B.; Wang, F.; Liu, J. K. Chin. Trad. Pat. Med. 2010, 32, 462 (in Chinese). doi: 10.3969/j.issn.1001-1528.2010.03.033
7. [7]
  Zhang, J.; Shen, P.; Lu, T.; Yu, D.; Li, H.; Yang, G. Z. Acta Chim. Sinica 2011, 69, 383 (in Chinese).
8. [8]
  Tchinda, A. T.; Mouokeu, S. R.; Ngono, R. A.; Ebelle, M. R.; Mokale, A. L.; Nono, D. K.; Frédérich, M. Nat. Prod. Res. 2015, 29, 1990. doi: 10.1080/14786419.2015.1022541
9. [9]
  Bui, M. L.; Grayer, R. J.; Veitch N. C.; Kiteb, G. C.; Trana, H.; Nguyena, Q. K. Biochem. Syst. Ecol. 2004, 32, 943. doi: 10.1016/j.bse.2004.03.001
10. [10]
  Fushiya, S.; Kishi, Y.; Hattori, K.; Batkhuu J.; Takano, F.; Singab, A. N.; Okuyama, T. Planta Med. 1999, 65, 404. doi: 10.1055/s-1999-14084
11. [11]
  Parmar, V. S.; Bisht, K. S.; Sharma, S. K.; Jain, R.; Taneja, P.; Singh, S.; Simonsen, O.; Boll, P. M. Phytochemistry 1994, 36, 507. doi: 10.1016/S0031-9422(00)97104-8
12. [12]
  Xu, N. S.; Yang, H. M.; Cui, M.; Song, F. R.; Liu, Z. Q.; Liu, S. Y. Chin. J. Chem. 2012, 30, 1433. doi: 10.1002/cjoc.v30.7
13. [13]
  Zhang, Y. L.; Jiang, L. L.; Xiao, T. S.; Li, Y. B. J. Asian. Nat. Prod. Res. 2015, 17, 717. doi: 10.1080/10286020.2014.992887
14. [14]
  Maldonado, E.; Toscano, R. A.; Mancera, C.; Tripp, M. T.; Ortega, A. Phytochemistry 1992, 31, 1003. doi: 10.1016/0031-9422(92)80203-Q
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