Citation: Wang Guokai, Sun Yunpeng, Wang Zheng, Zhang Nan, Wang Gang, Zhou Zhongyu, Liu Jinsong. Two New Flavonoids from Kalimeris integrifolia[J]. Chinese Journal of Organic Chemistry, ;2017, 37(4): 1016-1019. doi: 10.6023/cjoc201611021 shu

Two New Flavonoids from Kalimeris integrifolia

Wang Guokai ^a ,
Sun Yunpeng ^a ,
Wang Zheng ^a ,
Zhang Nan ^a ,
Wang Gang ^a,*,, ,
Zhou Zhongyu ^b ,
Liu Jinsong ^a,*,,

a.
Anhui Key Laboratory for mordern Chinese Materia Medica, School of Pharmacy, Anhui University of Chinese Medicine, Hefei 230012
b.
Guangdong Provincial Key Laboratory of Applied Botany, South China Botanical Garden, Chinese Academy of Sciences, Guangzhou 510650

Corresponding author: Wang Gang, jinsongliu108@sina.com Liu Jinsong, kunhong_8@163.com
Received Date: 18 November 2016
Revised Date: 13 December 2016

Fund Project: the Guangdong Provincial Key Laboratory of Applied Botany, South China Botanical Garden, CAS AB2015001the National Natural Science Foundation of China 81303220the Natural Sciences Foundation of Anhui Province 11040606M220

Figures(2)

Investigation on Kalimeris integrifolia resulted in two compounds by means of various chromatographic techniques (silica gel, Sephadex LH-20, RP-LC and Pre-HPLC). Their structures were determined as 5, 8-dihydroxy-2-(3-hydroxy-4, 5-dimethoxyphenyl)-6, 7-dimethoxy-4H-chromen-4-one (1) and 5-hydroxy-6, 7-dimethoxy-2-(4-methoxyphenyl)-4-oxo-4H-chromen-8-yl 2-methylbutanoate (2) on the basis of extensive spectroscopic analyses including MS, IR, UV, 1D-and 2D-NMR. Among them, compounds 1 and 2 are two new flavonoids, named as kalinturflavone A (1) and kalinturflavone B (2).
- Kalimeris integrifolia,
- Asteraceae,
- chemical constituent,
- flavonoids
1. [1]
  Chinese Flora Editorial Board of Chinese Academy of Sciences Flora of China, Vol. 74, Science Press, Beijing, 1985 (in Chinese).
2. [2]
  Chinese Herbal Editorial Board Chinese Herbal, Shanghai Science and Technology Press, Shanghai, 1999 (in Chinese).
3. [3]
  Ji, P.; Wang, G. K.; , Liu, J. S.; Luo, Z. H.; Liu, J. K.; Wang, G. Nat. Prod. Res. Dev. 2014, 26, 212 (in Chinese).
4. [4]
  Zhong, W. W.; Liu, J. S.; Zhang, C. E.; Chen A. M.; Xu, Y. S.; Wang G. Guihaia 2012, 32, 261 (in Chinese). doi: 10.3969/j.issn.1000-3142.2012.02.023
5. [5]
  Wang, G. K.; Liu, J. S.; Zhang, C. E.; Wang, Z.; Cai, B. X.; Wang, G. Chin. Med. Mater. 2015, 38, 82 (in Chinese).
6. [6]
  Liu, J. S.; Wang G.; Wang, G. K.; Yu, B.; Wang, F.; Liu, J. K. Chin. Trad. Pat. Med. 2010, 32, 462 (in Chinese). doi: 10.3969/j.issn.1001-1528.2010.03.033
7. [7]
  Zhang, J.; Shen, P.; Lu, T.; Yu, D.; Li, H.; Yang, G. Z. Acta Chim. Sinica 2011, 69, 383 (in Chinese).
8. [8]
  Tchinda, A. T.; Mouokeu, S. R.; Ngono, R. A.; Ebelle, M. R.; Mokale, A. L.; Nono, D. K.; Frédérich, M. Nat. Prod. Res. 2015, 29, 1990. doi: 10.1080/14786419.2015.1022541
9. [9]
  Bui, M. L.; Grayer, R. J.; Veitch N. C.; Kiteb, G. C.; Trana, H.; Nguyena, Q. K. Biochem. Syst. Ecol. 2004, 32, 943. doi: 10.1016/j.bse.2004.03.001
10. [10]
  Fushiya, S.; Kishi, Y.; Hattori, K.; Batkhuu J.; Takano, F.; Singab, A. N.; Okuyama, T. Planta Med. 1999, 65, 404. doi: 10.1055/s-1999-14084
11. [11]
  Parmar, V. S.; Bisht, K. S.; Sharma, S. K.; Jain, R.; Taneja, P.; Singh, S.; Simonsen, O.; Boll, P. M. Phytochemistry 1994, 36, 507. doi: 10.1016/S0031-9422(00)97104-8
12. [12]
  Xu, N. S.; Yang, H. M.; Cui, M.; Song, F. R.; Liu, Z. Q.; Liu, S. Y. Chin. J. Chem. 2012, 30, 1433. doi: 10.1002/cjoc.v30.7
13. [13]
  Zhang, Y. L.; Jiang, L. L.; Xiao, T. S.; Li, Y. B. J. Asian. Nat. Prod. Res. 2015, 17, 717. doi: 10.1080/10286020.2014.992887
14. [14]
  Maldonado, E.; Toscano, R. A.; Mancera, C.; Tripp, M. T.; Ortega, A. Phytochemistry 1992, 31, 1003. doi: 10.1016/0031-9422(92)80203-Q
1. [1]
  Weiliang Wang , Zijing Yu , Jingyuan Li , Hong Shang . The Debate between Traditional Chinese Medicine and Western Medicine. University Chemistry, 2024, 39(9): 109-114. doi: 10.12461/PKU.DXHX202402001
2. [2]
  Zhonghong Yan , Chunxia Li , Ruolin Yang . Analysis of the Use and Effectiveness of Concept Mapping Assignments in English Medium Instruction of General Chemistry. University Chemistry, 2025, 40(4): 224-231. doi: 10.12461/PKU.DXHX202405138
3. [3]
  Lijun Dong , Pengcheng Du , Guangnong Lu , Wei Wang . Exploration and Practice of Independent Design Experiments in Inorganic and Analytical Chemistry: A Case Study of “Preparation and Composition Analysis of Tetraammine Copper(II) Sulfate”. University Chemistry, 2024, 39(4): 361-366. doi: 10.3866/PKU.DXHX202310041
4. [4]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
5. [5]
  Yanglin Jiang , Mingqing Chen , Min Liang , Yige Yao , Yan Zhang , Peng Wang , Jianping Zhang . Experimental and Theoretical Investigations of Solvent Polarity Effect on ESIPT Mechanism in 4′-N,N-diethylamino-3-hydroxybenzoflavone. Acta Physico-Chimica Sinica, 2025, 41(2): 100012-. doi: 10.3866/PKU.WHXB202309027
6. [6]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
7. [7]
  Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . 倍增型全聚合物光电探测器及其在光电容积描记传感器上的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2311021-. doi: 10.3866/PKU.WHXB202311021
8. [8]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
9. [9]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
10. [10]
  Yuan Zheng , Quan Lan , Zhenggen Zha , Lingling Li , Jun Jiang , Pingping Zhu . Teaching Reform of Organic Synthesis Experiments by Introducing Reverse Thinking and Design Concepts: Taking the Synthesis of Cinnamic Acid Based on Retrosynthetic Analysis as an Example. University Chemistry, 2024, 39(6): 207-213. doi: 10.3866/PKU.DXHX202310065
11. [11]
  Juan Yang . Construction of General Chemistry Course in the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 8-13. doi: 10.12461/PKU.DXHX202408026
12. [12]
  Hongyan Chen , Yajun Hou , Shui Hu , Zhuoxun Wei , Fang Zhu , Chengyong Su . Construction of Synthetic Chemistry Experiment of the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 58-63. doi: 10.12461/PKU.DXHX202409109
13. [13]
  Yutao Lu , Jing Wu . Rebirth from the Flames: Unveiling the “Chemical Secrets” of Fire Smoke. University Chemistry, 2024, 39(9): 208-213. doi: 10.12461/PKU.DXHX202401001
14. [14]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
15. [15]
  Dongcheng Liu , Xiaokun Li , Huancheng Hu , Cunji Gao , Qiong Hu , Shuting Li , Yuning Liang . Chemistry Experimental Teaching Reform for the Promotion of Training Exceptional Chemistry Teachers for Normal Schools. University Chemistry, 2024, 39(8): 1-6. doi: 10.3866/PKU.DXHX202311072
16. [16]
  Bing Sun . Practice of Ideological and Political Education in Physical Chemistry Courses for Non-Chemistry Majors. University Chemistry, 2024, 39(8): 28-35. doi: 10.3866/PKU.DXHX202311080
17. [17]
  Jiaqi Chen , Chunhui Luan , Yue Sun , Qiyun Ma , Wangfei Hao , Yanjia Wang , Xu Wu . Understanding the Dynamics of Heat and Cold through Chemistry: The Interplay of Chemical Energy and Thermal Energy. University Chemistry, 2024, 39(9): 214-223. doi: 10.12461/PKU.DXHX202312020
18. [18]
  Qin Kuang , Lansun Zheng , Yaxian Zhu . Overall Design of the Inorganic Chemistry Course for the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 14-21. doi: 10.12461/PKU.DXHX202408071
19. [19]
  Yang Liu , Peng Chen , Lei Liu . Chemistry “101 Plan”: Design and Construction of Chemical Biology Textbook. University Chemistry, 2024, 39(10): 45-51. doi: 10.12461/PKU.DXHX202407085
20. [20]
  Shouyun Yu , Wenwei Zhang , Shunliu Deng , Weihong Li , Yanping Ren , Yijun Li , Yuan Chun , Houjin Li , Li Ma , Faqiong Zhao , Xiuqiong Zeng , Shuyong Zhang , Changgong Meng , Jianrong Zhang . Reflection and Practice on the Construction of Fundamental Chemistry Experiments under the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 52-57. doi: 10.12461/PKU.DXHX202408009

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(1036)
HTML views(111)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142