Citation: Li Xiaojin, Sun Yan, Zhang Lei, Peng Bo. Recent Progress in the Chemistry of Keteniminium Salts[J]. Chinese Journal of Organic Chemistry, ;2016, 36(11): 2530-2544. doi: 10.6023/cjoc201605046 shu

Recent Progress in the Chemistry of Keteniminium Salts

Li Xiaojin ^a ,
Sun Yan ^a ,
Zhang Lei ^a,*,, ,
Peng Bo ^a,b,*,,

a.
College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua 321004
b.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024

Corresponding author: Zhang Lei, lzhang@zjnu.cn Peng Bo, pengbo@zjnu.cn
Received Date: 31 May 2016
Revised Date: 16 August 2016

Fund Project: the State Key Laboratory of Fine Chemicals KF1512the National Natural Science Foundation of China 21502171the Educational Commission of Zhejiang Province Y201328123

Figures(32)

Keteniminium salts are unique heteroallenes. The high electrophility and cumulative double bonds render them versatile reactivity. This paper describes the keteniminium salts formed by electrophilic activation of amides or ynamides with non-metal electrophilic reagents. These keteniminium salts mainly undergo electrophilic addition, eletrophilic substitution, cycloaddition with various nucleophiles. In past few years, the study of keteniminium induced electrophilic rearrangement has progressed rapidly. The newly developed rearrangement transformations are also described here.
- keteniminium salts,
- electrophilic rearrangement,
- electrophilic substitution,
- cycloaddtion
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