Home

Citation: Xu Wenliang, Shan Lianhai, Huang Shuai, Li Suiyan, Zhou Xianli. New Ditetpenoid Alkaloid from the Whole Plant of Aconitum franchetii var. villosulum[J]. Chinese Journal of Organic Chemistry, ;2016, 36(11): 2739-2742. doi: 10.6023/cjoc201604055 shu

New Ditetpenoid Alkaloid from the Whole Plant of Aconitum franchetii var. villosulum

1.
School of Life Science and Engineering, Southwest Jiaotong University, Chengdu 610031

Corresponding author: Zhou Xianli, xxbiochem@163.com
Received Date: 26 April 2016
Revised Date: 21 June 2016

Fund Project: the Southwest Jiaotong University Graduate Students Creative Experiment YC201510102the Small Molecule Natural Medicine Innovation Team 15TD0048the Fundamental Research Funds for Central Universities 2682015YXZT03National Natural Science Foundation of China 81274193

Figures(3)

A new aconitine-type diterpenoid alkaloid, villosutine (1), was isolated from the whole plant of Aconitum franchetii var. villosulum, together with four other known aconitine-type diterpenoid alkaloids, one known pyro-type diterpenoid alkaloid and five known franchetine-type diterpenoid alkaloids. Their structures were elucidated on the basis of extensive spectroscopic analy-sis, including HR-ESIMS, 1D and 2D NMR experiments.
- aconitum,
- Aconitum franchetii var. villosulum,
- diterpenoid alkaloid,
- villosutine
1. [1]
  Xiao, P.-G.; Wang, F.-P.; Gao, F.; Yan, L.-P.; Chen, D.-L.; Liu, Y. Acta Phytotaxon. Sin. 2006, 44, 1 (in Chinese). doi: 10.1360/aps050046
2. [2]
  Institute of Botany, Chinese Academy of Sciences and Institute of Materia Medica, Chinese Academy of Medical Sciences Flora Reipublicae Populais Sinica, Vol. 27, Science Press, Beijing, 1979, p. 211 (in Chinese).
3. [3]
  Pelletier, S. W.; Mody, N. V.; Sawhney, R. S.; Bhattacharyya, J. Heterocycles 1977, 7, 327. doi: 10.3987/S-1977-01-0327
4. [4]
  Gabrieldela, F.; Rafael, D. A.; Tomas, O. Heterocycles 1989, 29, 205. doi: 10.3987/COM-89-4506
5. [5]
  Boido, V.; Edwards, O. E.; Handa, K. L.; Kolt, R. J. Can. J. Chem. 1984, 62, 778. doi: 10.1139/v84-130
6. [6]
  Pelletier, S. W.; Mody, N. V.; Puri, H. S. J. Chem. Soc., Chem. Commun. 1977, 1, 12
7. [7]
  Wang, F.-P.; Li, Z.-B.; Dai, X.-P.; Peng, C.-S. Phytochemstry 1997, 45, 1539. doi: 10.1016/S0031-9422(97)00164-7
8. [8]
  Peng, C.-S.; Dai, X.-P.; Chen, D.-L.; Wang, F.-P. Nat. Prod. Res. Dev. 1999, 11, 23 (in Chinese).
9. [9]
  Chen, D.-L.; Lin, L.-Y.; Chen, Q.-H.; Jian, X.-X.; Wang, F.-P. J. Asian Nat. Prod. Res. 2003, 5, 209. doi: 10.1080/1028602031000093393
10. [10]
  Chen, D.-L.; Chen, Q.-H.; Jian, X.-X.; Wang, F.-P. Nat. Prod. Res. Dev. 2002, 14, 6 (in Chinese).
11. [11]
  Zhang, F.; Peng, S.-L.; Luo, F.; Ding, L. Chin. Chem. Lett. 2005, 16, 1046.
12. [12]
  Chen, L.; Shan, L.-H.; Zhang, J.-F.; Xu, W.-L.; Wu, M.-Y.; Huang, S.; Zhou, X.-L. Nat. Prod. Commun. 2015, 10, 2063.
13. [13]
  Wang, F.-P. Chin. J. Org. Chem. 1982, 2, 161 (in Chinese).
1. [1]
  Yurong Tang , Yunren Shi , Yi Xu , Bo Qin , Yanqin Xu , Yunfei Cai . Innovative Experiment and Course Transformation Practice of Visible-Light-Mediated Photocatalytic Synthesis of Isoquinolinone. University Chemistry, 2024, 39(5): 296-306. doi: 10.3866/PKU.DXHX202311087
2. [2]
  Conghao Shi , Ranran Wang , Juli Jiang , Leyong Wang . The Illustration on Stereoisomers of Macrocycles Containing Multiple Chiral Centers via Tröger Base-based Macrocycles. University Chemistry, 2024, 39(7): 394-397. doi: 10.3866/PKU.DXHX202311034
3. [3]
  Jia-He Li , Yu-Ze Liu , Jia-Hui Ma , Qing-Xiao Tong , Jian-Ji Zhong , Jing-Xin Jian . 洛芬碱衍生物的合成、化学发光与重金属离子检测. University Chemistry, 2025, 40(6): 230-237. doi: 10.12461/PKU.DXHX202407080
4. [4]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-0. doi: 10.3866/PKU.WHXB202407005
5. [5]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
6. [6]
  Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154
7. [7]
  Bin SUN , Heyan JIANG . Glucose-modified bis-Schiff bases: Synthesis and bio-activities in Alzheimer′s disease therapy. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1338-1350. doi: 10.11862/CJIC.20240428
8. [8]
  Jianfeng Yan , Yating Xiao , Xin Zuo , Caixia Lin , Yaofeng Yuan . Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives. University Chemistry, 2024, 39(4): 329-337. doi: 10.3866/PKU.DXHX202310005
9. [9]
  Wei HE , Jing XI , Tianpei HE , Na CHEN , Quan YUAN . Application of solar-driven inorganic semiconductor-microbe hybrids in carbon dioxide fixation and biomanufacturing. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 35-44. doi: 10.11862/CJIC.20240364
10. [10]
  Xiaofei Liu , He Wang , Li Tao , Weimin Ren , Xiaobing Lu , Wenzhen Zhang . Electrocarboxylation of Benzylic Phosphates and Phosphinates with Carbon Dioxide. Acta Physico-Chimica Sinica, 2024, 40(9): 2307008-0. doi: 10.3866/PKU.WHXB202307008
11. [11]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
12. [12]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . Thickness-Insensitive, Cyano-Modified Perylene Diimide Derivative as a Cathode Interlayer Material for High-Efficiency Organic Solar Cells. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-0. doi: 10.3866/PKU.WHXB202406007
13. [13]
  Keweiyang Zhang , Zihan Fan , Liyuan Xiao , Haitao Long , Jing Jing . Unveiling Crystal Field Theory: Preparation, Characterization, and Performance Assessment of Nickel Macrocyclic Complexes. University Chemistry, 2024, 39(5): 163-171. doi: 10.3866/PKU.DXHX202310084
14. [14]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
15. [15]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
16. [16]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
17. [17]
  Zhilian Liu , Wengui Wang , Hongxiao Yang , Yu Cui , Shoufeng Wang . Ideological and Political Education Design for the Synthesis of Irinotecan Drug Intermediate 7-Ethyl Camptothecin. University Chemistry, 2024, 39(2): 89-93. doi: 10.3866/PKU.DXHX202306012
18. [18]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
19. [19]
  Xiaotong LU , Pan ZHANG , Zijie ZHAO , Lei HUANG , Hongwei ZUO , Lili LIANG . Antitumor and antibacterial activities of pyridyl Schiff base indium and dysprosium complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1523-1532. doi: 10.11862/CJIC.20250073
20. [20]
  . . Chinese Journal of Inorganic Chemistry, 2024, 40(12): 0-0.

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1345)
HTML views(93)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return