Citation: Song Chuang, Mao Guoliang, Liu Zhenhua, Ning Yingnan, Jiang Tao. Advances in Mechanistic Research of Ethylene Selective Oligomeri-zation Catalyzed by Homogeneous Chromium-Based Catalysts[J]. Chinese Journal of Organic Chemistry, ;2016, 36(9): 2105-2120. doi: 10.6023/cjoc201602034 shu

Advances in Mechanistic Research of Ethylene Selective Oligomeri-zation Catalyzed by Homogeneous Chromium-Based Catalysts

a.
Provincial Key Laboratory of Oil & Gas Chemical Technology, College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318
b.
College of Material Science and Chemical Engineering, Tianjin University of Science & Technology, Tianjin 300222

Corresponding author: Mao Guoliang, maoguoliang@nepu.edu.cn
Received Date: 29 February 2016
Revised Date: 21 April 2016

Fund Project: Project supported by the National Natural Science Foundation of China 51534004the Program for New Century Excellent Talents in University NCET-07-0142Project supported by the National Natural Science Foundation of China U1362110

Figures(22)

Linear α-olefin is an important feed stock for chemical industry. Production of specific α-olefin through selective ethylene oligomerization catalyzed by homogeneous chromium-based catalysts is an important research on orientation under rapid development in recent years. The research of catalytic mechanism plays an important role in guiding the exploration of novel high-efficient catalysts. The application of methods such as labelled atom, organometallic precursor, EPR-XAS, density functional theory (DFT) calculation etc. in the research of reaction path and the metal oxidation state is introduced, with the latest achievement in the mechanistic research summarized. Research works carried out by various researchers are compared and discussed from methodology. New perspective on binuclear Cr metal ring mechanistic research is proposed and an outlook on the further research orientation is presented.
- ethylene,
- chromium-based catalyst,
- metal complex,
- catalyst activation,
- selective oligomerization,
- mechanism research
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沈阳化工大学材料科学与工程学院沈阳 110142