Citation: Pan Lingxiang, Luo Wenwen, Chen Ming, Liu Junkai, Xu Lu, Hu Rongrong, Zhao Zujin, Qin Anjun, Tang BenZhong. Tetraphenylpyrazine-Based Luminogens with Aggregation-Enhanced Emission Characteristics: Preparation and Property[J]. Chinese Journal of Organic Chemistry, ;2016, 36(6): 1316-1324. doi: 10.6023/cjoc201602020 shu

Tetraphenylpyrazine-Based Luminogens with Aggregation-Enhanced Emission Characteristics: Preparation and Property

Pan Lingxiang ^a ,
Luo Wenwen ^a ,
Chen Ming ^b ,
Liu Junkai ^a ,
Xu Lu ^a ,
Hu Rongrong ^a ,
Zhao Zujin ^a ,
Qin Anjun ^a,*,, ,
Tang BenZhong ^a,b,*,,

a.
State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640
b.
Hong Kong Branch of National Engineering Research Center for Tissue Restoration & Reconstruction, Department of Chemistry, The Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong

Corresponding author: Qin Anjun, msqinaj@scut.edu.cn Tang BenZhong, tangbenz@ust.hk
Received Date: 22 February 2016
Revised Date: 3 April 2016

Fund Project: Project supported by the National Natural Science Foundation of China No.21525417and the National Program for Support of Top-Notch Young Professionals and the Guangdong Innovative Research Team Program No.201101C0105067115the National Key Basic Research Program of China (973 Program) No.2013CB834702

Figures(6)

The research on aggregation-induced emission (AIE) has been a hot topic in the fields of photo-physics and luminescent materials. Design and synthesis of new AIE-active luminogens (AIEgens) will further promote the development of this area. Based on our developed new AIEgen of tetraphenylpyrazine (TPP), in this paper, we further enriched its family by covalently attaching thiophene unit on TPP core, and prepared three AIEgens of TPP-T, TPP-2T and T-TPP-T. Their structure-property relationship was studied in detail. The results showed that TPP-T, TPP-2T and T-TPP-T feature the aggregation-enhanced emission (AEE) characteristics. Their powders emit at 418, 437 and 436 nm with absolute fluorescence quantum yields of 26.8, 29.0 and 30.9%, respectively, which makes them promising to be used as emitting layer in fabrication of organic light-emitting diodes in combination with their excellent thermal stability.
- tetraphenylpyrazine,
- aggregation-enhanced emission (AEE),
- structure-property relationship
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