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Citation: Wu Jiang, Zhou Junpeng, Shi Yalei, Zhu Jintao. Study on Chlorination Reaction of Aromatic Aldehydes with Phenylphosphonic Dichloride[J]. Chinese Journal of Organic Chemistry, ;2016, 36(8): 1958-1962. doi: 10.6023/cjoc201601046 shu

Study on Chlorination Reaction of Aromatic Aldehydes with Phenylphosphonic Dichloride

1.
Department of Chemistry, Zhejiang Sci-Tech University, Hangzhou 310018

Corresponding author: Zhu Jintao, zhujintao1968@163.com
Received Date: 31 January 2016
Revised Date: 14 March 2016

Figures(2)

A conversion of aromatic aldehydes to dichloromethylated or trichloromethylated aromatics has been firstly accomplished by using phosphorus pentachloride as the chlorination agent. In this reaction, dichloromethylated aromatics can be obtained alone when it keeps constantly blowing oxygen into the reaction solution, and 2-methylpropionitrule can also be used to promote the formation of trichloromethylated aromatics. And it has provided a new method of highly efficient synthesis for dichloromethylated aromatics and trichloromethylated aromatics in good yields.
- phosphorus pentachloride,
- oxygen,
- 2-methylpropionitrule,
- dichloromethylated aromatics,
- trichloromethylated aromatics
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