Citation: Li Xuedong, Lang Xiandong, Song Qingwen, Guo Yakun, He Liangnian. Cu(I)-Catalyzed Three-Component Reaction of Propargylic Alcohol, Secondary Amines and Atmospheric CO₂[J]. Chinese Journal of Organic Chemistry, ;2016, 36(4): 744-751. doi: 10.6023/cjoc201512037 shu

Cu(I)-Catalyzed Three-Component Reaction of Propargylic Alcohol, Secondary Amines and Atmospheric CO₂

1.
State Key Laboratory and Institute of Elemento-Organic. Chemistry, Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, Tianjin 300071

Corresponding author: He Liangnian,
Received Date: 25 December 2015
Available Online: 30 January 2016
Fund Project: 国家自然科学基金(Nos.21472103,21121002) (Nos.21472103,21121002)教育部博士点基金(No.20130031110013) (No.20130031110013)国家基础科学人才培养基金(No.J1103306)资助项目. (No.J1103306)

β-Oxopropylcarbamates constitute an important kind of organic compounds, owing to the extensive applications in agrochemicals, pharmaceuticals, organic synthesis, and protection of amino group. In this article, an efficient and atom-economical Cu(I) catalyzed three-component reaction of propargylic alcohols, secondary amines and CO₂ has been developed under atmospheric pressure, affording various β-oxopropylcarbamates in high yields with high selectivity by controlling the concentration of O₂. This protocol avoids the use of high pressure of CO₂ and provides an extremely simple way to access the synthetically useful β-oxopropylcarbamates.
- CO₂,
- homogeneous catalysis,
- synthetic methods,
- Cu,
- three-component reaction,
- β-oxopropylcarbamates
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Cu(I)-Catalyzed Three-Component Reaction of Propargylic Alcohol, Secondary Amines and Atmospheric CO2

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通讯作者: 陈斌, bchen63@163.com

Cu(I)-Catalyzed Three-Component Reaction of Propargylic Alcohol, Secondary Amines and Atmospheric CO₂