Citation: Zhou Wenjun, Wang Dan, Zhang Xiazhong, Zeng Bin. Preparation and Catalytic Properties of a Novel Bamboo Fiber Supported-Palladium Catalyst (Fiber-Pd)[J]. Chinese Journal of Organic Chemistry, ;2016, 36(6): 1412-1418. doi: 10.6023/cjoc201510037 shu

Preparation and Catalytic Properties of a Novel Bamboo Fiber Supported-Palladium Catalyst (Fiber-Pd)

Zhou Wenjun ^a,b ,
Wang Dan ^a ,
Zhang Xiazhong ^a,b,*,, ,
Zeng Bin ^a

a.
College of Chemistry and Chemical Engineering, Neijiang Normal University, Neijiang 641112
b.
Key Laboratory of Fruit Waste Treatment and Resource Recycling of the Sichuan Provincial College, Sichuan 641112

Corresponding author: Zhang Xiazhong, chemzhwj@126.com
Received Date: 29 October 2015
Revised Date: 30 January 2016

Fund Project: and the Startup Foundation of Ph. D. Scientific Research of Neijiang Normal University No. 2012B05Project supported by the Sichuan Province Education Office Fostering Projects No. 15CZ0026the Youth Found of Sichuan Province Education Office Nos. 12ZB074, 13ZB0002, 11ZB024

Figures(5)

A novel bamboo fiber supported palladium (Fiber-Pd) catalyst was prepared with diphenylphosphinite fiber and palladium dichloride in ethanol. The as-prepared Fiber-Pd catalyst was characterized by X-ray photoelectron spectrometer (XPS), X-ray diffraction (XRD), thermogravimetric analyses (TGA), inductively coupled plasma-atomic emission spectrometry (ICP-AES), and transmission electron microscopy (TEM). The catalyst was applied to the Suzuki cross-coupling reaction between sodium tetraarylborate and aryl halides. Excellent yields of the corresponding functionalized biaryls were obtained when the reaction was performed in the presence of NaHCO₃ as base in PEG 400/H₂O at 85 ℃ within a short reaction time. It is noteworthy that the present protocol is highly efficient as 4 equiv. aryl halides reacted with 1 equiv. sodium tetraarylborate cleanly to provide high yield of the cross-coupling products in short reaction time. The catalyst can be easily separated and recovered from the reaction mixture by filtration and reused. This process has significant features of short reaction time, broad substrate scopes, easy isolation of the product, and atom-efficient coupling under mild conditions in environmentally friendly media in air.
- bamboo fiber supported palladium,
- preparation,
- Suzuki reaction,
- sodium tetraphenylborate,
- aryl halide
1. [1]
  Miyaura, N.; Yanagi, T.; Suzuki, A. Synth. Commun. 1981, 11, 513.
2. [2]
  Miyaura, N.; Yamada, K.; Suzuki, A. Tetrahedron Lett. 1979, 20, 3437.
3. [3]
  Suzuki, A. Pure Appl. Chem. 1991, 63, 419.
4. [4]
  Miyaura, N.; Suzuki, A. Chem. Rev. 1995, 95, 2457.
5. [5]
  Suzuki, A. J. Organomet. Chem. 1999, 576, 147.
6. [6]
  Hassan, J.; Sévignon, M.; Gozzi, C.; Schulz, E.; Lemaire, M. Chem. Rev. 2002, 102, 1359.
7. [7]
  Molander, G. A.; Ellis, N. Acc. Chem. Res. 2007, 40, 275.
8. [8]
  Kantchev, E. A. B.; O'Brien, C. J.; Organ, M. G. Angew. Chem., Int. Ed. 2007, 46, 2768.
9. [9]
10. [10]
11. [11]
  Cole-Hamiton, D. J. Science 2003, 299, 1702.
12. [12]
  Trost, B. M.; Keinan, E. J. Am. Chem. Soc. 1978, 100, 7779.
13. [13]
  Terasawa, M.; Kaneda, K.; Imanaka, T.; Teranishi, S. J. Organomet. Chem. 1978, 162, 403.
14. [14]
  Lamblin, M.; Hardy-Nassar, L.; Hierso, J.-C.; Fouquet, E.; Felpin, F.-X. Adv. Synth. Catal. 2010, 352, 33.
15. [15]
  Yin, L.; Liebscher, J. Chem. Rev. 2007, 107, 133.
16. [16]
  Reddy, K. R.; Kumar, N. S.; Reddy, P. S. J. Mol. Catal. A: Chem. 2006, 252, 12.
17. [17]
  Cirtiu, C. M.; Dunlop-Briere, A. F.; Moores, A. Green Chem. 2011, 13, 288.
18. [18]
19. [19]
20. [20]
  Du, Q.; Li, Y. Beilstein J. Org. Chem, 2011, 7, 378.
21. [21]
  Du, Q.; Li, Y. Res. Chem. Intermed. 2012, 38, 1807.
22. [22]
  Wang, X.; Xu, Y.; Wang, F.; Wei, Y. J. Appl. Polym. Sci. 2015, 132, 41427/1-41427/8.
23. [23]
  Vaddula, B. R.; Saha, A.; Varma, R. S.; Leazer, J. Eur. J. Org. Chem. 2012, 6707.
24. [24]
25. [25]
  Majumdar, A.; Mukhopadhyay, S.; Yadav, R. Int. J. Therm. Sci. 2010, 49, 2042.
26. [26]
27. [27]
  Zhou W.-J.; Wang, K.; Wang, J.-X. Adv. Synth. Catal. 2009, 351, 1378.
28. [28]
29. [29]
  Son, S. U.; Jang, Y. G.; Park, J.; Na, H. B.; Park, H. M.; Yun, H. J.; Lee, J.; Hyeon, T. J. Am. Chem. Soc., 2004, 126, 5026.
1. [1]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
2. [2]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030
3. [3]
  Qiuping Liu , Yongxian Fan , Wenxian Chen , Mengdi Wang , Mei Mei , Genrong Qiang . Design of Ideological and Political Education for the Preparation Experiment of Ferrous Sulfate. University Chemistry, 2024, 39(2): 116-120. doi: 10.3866/PKU.DXHX202309083
4. [4]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
5. [5]
  Yufan Pan , Xue Ding , Jiayu Lin , Haiting Wu , Hairong Huang , Cuixue Chen , Meiling Ye . Oil Cosmetics, Charming Chemistry: A Gradient Science Popularization Scheme for Cream Cosmetic Preparation. University Chemistry, 2025, 40(4): 382-389. doi: 10.12461/PKU.DXHX202406078
6. [6]
  Lingqi Zhang , Hairong Huang , Jialin Li , Li Ji , Yufan Pan , Meiling Ye , Cuixue Chen , Shunü Peng . 桂花碳量子点的绿色制备及科普应用方案. University Chemistry, 2025, 40(8): 298-306. doi: 10.12461/PKU.DXHX202409138
7. [7]
  Xinzhe HUANG , Lihui XU , Yue YANG , Liming WANG , Zhangyong LIU , Zhongjian WANG . Preparation and visible light responsive photocatalytic properties of BiSbO₄/BiOBr. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 284-292. doi: 10.11862/CJIC.20240212
8. [8]
  Bolin Sun , Jie Chen , Ling Zhou . 乙烯型卤代烃的亲核取代反应. University Chemistry, 2025, 40(8): 152-157. doi: 10.12461/PKU.DXHX202410032
9. [9]
  Zhongyan Cao , Youzhi Xu , Menghua Li , Xiao Xiao , Xianqiang Kong , Deyun Qian . Electrochemically Driven Denitrative Borylation and Fluorosulfonylation of Nitroarenes. University Chemistry, 2025, 40(4): 277-281. doi: 10.12461/PKU.DXHX202407017
10. [10]
  Daojuan Cheng , Fang Fang . Exploration and Implementation of Science-Education Integration in Organic Chemistry Teaching for Pharmacy Majors: A Case Study on Nucleophilic Substitution Reactions of Alkyl Halides. University Chemistry, 2024, 39(11): 72-78. doi: 10.12461/PKU.DXHX202403105
11. [11]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
12. [12]
  Xiuyun Wang , Jiashuo Cheng , Yiming Wang , Haoyu Wu , Yan Su , Yuzhuo Gao , Xiaoyu Liu , Mingyu Zhao , Chunyan Wang , Miao Cui , Wenfeng Jiang . Improvement of Sodium Ferric Ethylenediaminetetraacetate (NaFeEDTA) Iron Supplement Preparation Experiment. University Chemistry, 2024, 39(2): 340-346. doi: 10.3866/PKU.DXHX202308067
13. [13]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024
14. [14]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223
15. [15]
  Hongting Yan , Aili Feng , Rongxiu Zhu , Lei Liu , Dongju Zhang . Reexamination of the Iodine-Catalyzed Chlorination Reaction of Chlorobenzene Using Computational Chemistry Methods. University Chemistry, 2025, 40(3): 16-22. doi: 10.12461/PKU.DXHX202403010
16. [16]
  Ling Liu , Haibin Wang , Genrong Qiang . Curriculum Ideological and Political Design for the Comprehensive Preparation Experiment of Ethyl Benzoate Synthesized from Benzyl Alcohol. University Chemistry, 2024, 39(2): 94-98. doi: 10.3866/PKU.DXHX202304080
17. [17]
  Wanmin Cheng , Juan Du , Peiwen Liu , Yiyun Jiang , Hong Jiang . Photoinitiated Grignard Reagent Synthesis and Experimental Improvement in Triphenylmethanol Preparation. University Chemistry, 2024, 39(5): 238-242. doi: 10.3866/PKU.DXHX202311066
18. [18]
  Yan'e LIU , Shengli JIA , Yifan JIANG , Qinghua ZHAO , Yi LI , Xinshu CHANG . MoO₃/cellulose derived carbon aerogel: Fabrication and performance as cathode for lithium-sulfur battery. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1565-1573. doi: 10.11862/CJIC.20250054
19. [19]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
20. [20]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(662)
HTML views(73)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142