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Citation: Zhang Hao, Huang Long, Li Tao, Liu Bin, Bai Zeming, Li Xiaona, Lu Dan. Quantitative Structure-property Relationship of Polyfluorene Conjugated Polymers Condensed State from Solution to Film[J]. Acta Chimica Sinica, ;2019, 77(5): 397-405. doi: 10.6023/A19010039 shu

Quantitative Structure-property Relationship of Polyfluorene Conjugated Polymers Condensed State from Solution to Film

  • State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012

  • Corresponding author: Lu Dan, lud@jlu.edu.cn
  • Received Date: 25 December 2018
    Available Online: 20 May 2019

    Fund Project: the National Natural Science Foundation of China 91333103Project supported by the National Natural Science Foundation of China (Nos. 21174049, 91333103, 21574053)the National Natural Science Foundation of China 21174049the National Natural Science Foundation of China 21574053

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  • Polyfluorenes are not only a class of classical blue conjugated polymers with high fluorescence efficiency and good thermal stability, but also a hairy-rod polymer model due to their rigid main chain and flexible side chain. Therefore, PFs have received attention and related reports are continuing. Most of the research on PFs has focused on the synthesis of new functional materials and the improvement of device structure to improve their photoelectric properties. However, the research on single chain conformation, chain aggregation structure, film condensed structure and photovoltaic devices performance in the process of precursor solution to film are rarely reported. In recent years, our research group focused on the quantitative structure-property relationship of polyfluorene conjugated polymers condensed state from solution to film. The complex single chain and aggregate shape characteristics of PFs precursor solutions were studied by static/dynamic laser scattering and other methods. Combining spectroscopy, electron microscopy and other methods, the kinetic evolution of PFs in isolated single chain, aggregation condensed-structures, transition state and the mechanism and regularity of β-conformation are revealed. Quantitative structure-property relationship of single-chain conformation of precursor solution, aggregate structure of thin film and optoelectronic device performance is established. The aim is to improve the photoelectric efficiency of the polymer from the intrinsic properties. The research will have important guiding significance not only for polyfluorene-based polymers but also for the design and processing of the entire conjugated polymer materials.
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    1. [1]

      Friend, R. H.; Gymer, R. W.; Holmes, A. B.; Burroughes, J. H.; Marks, R. N.; Taliani, C.; Bradley, D. D. C.; Dos Santos, D. A.; Brédas, J. L.; Lögdlund, M.; Salaneck, W. R. Nature 1999, 397, 121.  doi: 10.1038/16393

    2. [2]

      Cheng, Y.-J.; Yang, S.-H.; Hsu, C.-S. Chem. Rev. 2009, 109(11), 5868.  doi: 10.1021/cr900182s

    3. [3]

      McGehee, M. D.; Heeger, A. J. Adv. Mater. 2000, 12(22), 1655.  doi: 10.1002/(ISSN)1521-4095

    4. [4]

      Jia, T.; Zheng, N.-N.; Cai, W.-Q.; Ying, L.; Huang, F. Acta Chim. Sinica 2017, 75(8), 808(in Chinese).
       

    5. [5]

      Liu, Y.; Yuan, J.; Zou, Y.-P.; Li, Y.-F. Acta Chim. Sinica 2017, 75(3), 257(in Chinese).  doi: 10.3969/j.issn.0253-2409.2017.03.001
       

    6. [6]

      Liang, L.; Liu, L.-N.; Chen, X.-Q.; Xiang, X.; Lin, Q.; Lu, Z.-Q.; Li, J.-J.; Li, W.-S. Chin. J. Org. Chem. 2019, 39(1), 157(in Chinese).
       

    7. [7]

      Xie, L.-H.; Yang, S.-H.; Lin, J.-Y.; Yi, M.-D.; Huang, W. Philos. Trans. R. Soc. A Math. Phys. Eng. Sci. 2013, 371, 2000.

    8. [8]

      Dudek, S. P.; Pouderoijen, M.; Abbel, R.; Schenning, A. P. H. J.; Meijer, E. W. J. Am. Chem. Soc. 2005, 127(33), 11763.  doi: 10.1021/ja052054k

    9. [9]

      Pei, J.; Liu, X.-L.; Chen, Z.-K.; Zhang, X.-H.; Lai, Y.-H.; Huang, W. Macromolecules 2003, 36(2), 323.  doi: 10.1021/ma020744s

    10. [10]

      Smela, E.; Jager, E. W. H.; Inganas, O.; Smela, E.; Inganäs, O. Science 2000, 290, 1540.  doi: 10.1126/science.290.5496.1540

    11. [11]

      Kim, J. Y.; Lee, K.; Coates, N. E.; Moses, D.; Nguyen, T. Q.; Dante, M.; Heeger, A. J. Science 2007, 317, 222.  doi: 10.1126/science.1141711

    12. [12]

      Cui, H.-N.; Qiu, F.; Peng, J. Acta Chim. Sinica 2018, 76(9), 691(in Chinese).
       

    13. [13]

      Lin, D.-Y.; Song, S.-C.; Chen, Z.-Y.; Guo, P.-R.; Chen, J.-H.; Shi, H.-H.; Mai, Y.-L.; Song, H.-C. Chin. J. Org. Chem. 2018, 38(1), 103(in Chinese).
       

    14. [14]

      Pan, B.; Zhu, Y.-Z.; Qiu, C.-J.; Wang, B.; Zheng, J.-Y. Acta Chim. Sinica 2018, 76(3), 215(in Chinese).
       

    15. [15]

      Cui, J.-J. Chin. J. Org. Chem. 2018, 38(11), 2888(in Chinese).

    16. [16]

      Zheng, Y. Q.; Yao, Z. F.; Lei, T.; Dou, J. H.; Yang, C. Y.; Zou, L.; Meng, X.; Ma, W.; Wang, J. Y.; Pei, J. Adv. Mater. 2017, 29(42), 1701072.
       

    17. [17]

      Samuelsen, E. J.; Breiby, D. W.; Konovalov, O.; Struth, B.; Smilgies, D. Synth. Met. 2001, 123, 165.  doi: 10.1016/S0379-6779(00)01317-5

    18. [18]

      Neher, D. Macromol. Rapid Comm. 2001, 22, 1365.  doi: 10.1002/(ISSN)1521-3927

    19. [19]

      Scherf, U.; List, E. J. W. Adv. Mater.2002, 14(7), 477.  doi: 10.1002/(ISSN)1521-4095

    20. [20]

      Marsitzky, D.; Murray, J.; Scott, J. C.; Carter, K. R. Chem. Mater. 2001, 13(11), 4285.  doi: 10.1021/cm010282h

    21. [21]

      Klärner, G.; Lee, J. I.; Davey, M. H.; Miller, R. D. Adv. Mater. 1999, 11(2), 115.  doi: 10.1002/(ISSN)1521-4095

    22. [22]

      Zeng, G.; Yu, W. L.; Chua, S. J.; Huang, W. Macromolecules 2002, 35(18), 6907.  doi: 10.1021/ma020241m

    23. [23]

      Hayer, A.; Khan, A. L. T.; Friend, R. H.; Köhler, A. Phys. Rev. B-Condens. Matter Mater. Phys. 2005, 71(24), 241302.  doi: 10.1103/PhysRevB.71.241302

    24. [24]

      Ballauff, M. Macromolecules 1986, 19(5), 1366.  doi: 10.1021/ma00159a015

    25. [25]

      Grell, M.; Bradley, D. D. C.; Long, X.; Chamberlain, T.; Inbasekaran, M.; Woo, E. P.; Soliman, M. Acta Polym. 1998, 49, 439.  doi: 10.1002/(ISSN)1521-4044

    26. [26]

      Knaapila, M.; Almásy, L.; Garamus, V. M.; Ramos, M. L.; Justino, L. L. G.; Galbrecht, F.; Preis, E.; Scherf, U.; Burrows, H. D.; Monkman, A. P. Polymer 2008, 49(8), 2033.  doi: 10.1016/j.polymer.2008.02.046

    27. [27]

      Lu, H. H.; Liu, C. Y.; Chang, C. H.; Chen, S. A. Adv. Mater. 2007, 19(18), 2574.  doi: 10.1002/(ISSN)1521-4095

    28. [28]

      Peet, J.; Brocker, E.; Xu, Y.; Bazan, G. C. Adv. Mater. 2008, 20(10), 1882.  doi: 10.1002/(ISSN)1521-4095

    29. [29]

      Huang, L.; Huang, X.; Sun, G.; Gu, C.; Lu, D.; Ma, Y. J. Phys. Chem. C 2012, 116(14), 7993.  doi: 10.1021/jp301102t

    30. [30]

      Hirata, S.; Lee, T. J.; Head-Gordon, M. J. Chem. Phys. 1999, 111(19), 8904.
       

    31. [31]

      Li, T.; Huang, L.; Bai, Z.; Li, X.; Liu, B.; Lu, D. Polymer 2016, 88, 71.  doi: 10.1016/j.polymer.2016.02.015

    32. [32]

      Huang, L.; Li, T.; Liu, B.; Zhang, L.; Bai, Z.; Li, X.; Huang, X.; Lu, D. Soft Matter 2015, 11(13), 2627.  doi: 10.1039/C5SM00074B

    33. [33]

      Dai, S.; Tam, K. C.; Jenkins, R. D. Macromolecules 2000, 33(2), 404.  doi: 10.1021/ma990887n

    34. [34]

      Niu, A.; Liaw, D. J.; Sang, H. C.; Wu, C. Macromolecules 2000, 33(9), 3492.  doi: 10.1021/ma991622b

    35. [35]

      Raspaud, E.; Lairez, D.; Adam, M.; Carton, J. P. Macromolecules 1994, 27(11), 2956.
       

    36. [36]

      Zhang, G.; Niu, A.; Peng, S.; Jiang, M.; Tu, Y.; Li, M.; Wu, C. Acc. Chem. Res. 2001, 34(3), 249.  doi: 10.1021/ar000011x

    37. [37]

      Huang, Z.; Huang, Y.; Li, X.; Zhang, L. Carbohydr. Polym. 2009, 78(3), 596.  doi: 10.1016/j.carbpol.2009.05.027

    38. [38]

      Li, T.; Liu, B.; Zhang, H.; Ren, J.; Bai, Z.; Li, X.; Ma, T.; Lu, D. Polymer 2016, 103, 299.  doi: 10.1016/j.polymer.2016.09.072

    39. [39]

      Li, N.; Li, Y.; Wang, X. Macromolecules 2011, 44(21), 8598.

    40. [40]

      Li, T.; Lu, D. Acta Chim. Sinica 2016, 74, 649(in Chinese).  doi: 10.11862/CJIC.2016.076
       

    41. [41]

      Li, X.; Bai, Z.; Liu, B.; Li, T.; Lu, D. J. Phys. Chem. C 2017, 121, 14443.  doi: 10.1021/acs.jpcc.7b03370

    42. [42]

      Liu, B.; Li, T.; Zhang, H.; Ma, T.; Ren, J.; Liu, B.; Liu, B.; Lin, J.; Yu, M.; Xie, L.; Lu, D. J. Phys. Chem. C 2018, 122(26), 14814.  doi: 10.1021/acs.jpcc.8b03504

    43. [43]

      Bai, Z.; Liu, Y.; Li, T.; Li, X.; Liu, B.; Liu, B.; Lu, D. J. Phys. Chem. C 2016, 120(49), 27820.  doi: 10.1021/acs.jpcc.6b08941

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