Citation: Yue Guozong, Gao Rui, Zhao Pengxiang, Chu Mingfu, Shuai Maobing. Trivalent Uranium Complex in Small Molecules Activation[J]. Acta Chimica Sinica, ;2016, 74(8): 657-663. doi: 10.6023/A16050260 shu

Trivalent Uranium Complex in Small Molecules Activation

1.
Institute of Materials, China Academy of Engineering Physics, Mianyang 621908

Corresponding author: Shuai Maobing, shuaimaobing@caep.cn
Received Date: 26 May 2016

Fund Project: the National Natural Science Foundation of China 21601166the National Natural Science Foundation of China 21501156the National Natural Science Foundation of China 51573172the Discipline Development Foundation of Science and Technology on Surface Physics and Chemistry Laboratory ZDXKFZ201506

Figures(12)

Uranium, one of typical actinide elements, has strong polarizing property. Using 5f orbitals for bonding with ligands, uranium(III) compounds have some unique reactivities including: migratory insertion, σ-bond metathesis and redox activity etc., which provides researchers with good opportunities to obtain organic uranium complexes or materials with unique structures and reactional properties. In the last 20 years, it has been found that trivalent uranium organic complexes exhibit a wide variety of activation towards small molecules. Due to the significant research and potential industrial value, this field has been well developed in recent years. Some research results for small molecules (such as N₂, CO, CO₂) activation promoted by trivalent uranium complexes were summarized in the paper.
- actinide chemistry,
- trivalent uranium complex,
- coordination chemistry,
- activation of N₂, CO and CO₂
1. [1]
  Shi W. Q., Zhao Y. L., Chai Z. F.Prog. Chem., 2011, 23:1478.
2. [2]
  Yuan Y. L., Shi W. Q., Lan J. H., Chai Z. F.Chin. Sci. Bull., 2012, 57:581. doi: 10.1360/972011-2513
3. [3]
  Monreal M. J., Diaconescu P. L.Nat. Chem., 2010, 2:424. doi: 10.1038/nchem.642
4. [4]
  Jones C. J.d-and f-Block Chemistry, Polestar Wheatons, Exeter, 2001 p.86.
5. [5]
  Ephritikhine M.Dalton Trans. 2006, 2501.
6. [6]
  Fox A. R., Bart S. C., Meyer K., Cummins C. C.Nature, 2008, 455:341. doi: 10.1038/nature07372
7. [7]
  Liddle S. P.Angew. Chem., Int. Ed., 2015, 54:30.
8. [8]
  Fortier S., Hayton T. W.Coord. Chem. Rev., 2010, 254:197. doi: 10.1016/j.ccr.2009.06.003
9. [9]
  Altmaier M., Gaona X., Fanghänel T.Chem. Rev., 2013, 113:901. doi: 10.1021/cr300379w
10. [10]
  Loiseau. T.; Mihalcea I., Henry N., Volkringer C.Coord. Chem. Rev. 2014, 266～267, 69.
11. [11]
  Gardner B. M., Liddle S. T.Eur. J. Inorg. Chem. 2013, 3753.
12. [12]
  Jones M. B., Gaunt A. J.Chem. Rev., 2013, 113:1137. doi: 10.1021/cr300198m
13. [13]
  Arnold P. L., McMullon M. W., Rieb J., Kuhn F. E.Angew. Chem., Int. Ed., 2014, 53:2. doi: 10.1002/anie.v53.1
14. [14]
  Karmel I. S. R., Fridman N., Tamm M., Eisen M. S.J. Am. Chem. Soc., 2014, 136:17180. doi: 10.1021/ja5091436
15. [15]
  Karmel I. S. R., Fridman N., Eisen M. S.Organometallics, 2015, 34:636. doi: 10.1021/om501179e
16. [16]
  Ossola F., Zanella P., Ugo P., Seeber R.Inorg. Chim. Acta, 1988, 147:123. doi: 10.1016/S0020-1693(00)80640-4
17. [17]
  Avens L. R., Barnhart D. M., Burns C. J., McKee S. D., Smith W. H.Inorg. Chem., 1994, 33:4245. doi: 10.1021/ic00097a010
18. [18]
  Morris D. E., Re R. E. D., Jantunen K. C., Castro-Rodriguez I., Kiplinger J. L.Organometallics, 2004, 23:5142. doi: 10.1021/om049634v
19. [19]
  Haber F.DE 229126, 1909.
20. [20]
  Roussel P., Hitchcock P. B., Tinker N., Scott P.Chem. Commun., 1996, 17:2053.
21. [21]
  Odom A. L., Arnold P. L., Cummins C. C.J. Am. Chem. Soc., 1998, 120:5836. doi: 10.1021/ja980095t
22. [22]
  Cloke F. G. N., Hitchcock P. B. J.Am. Chem. Soc., 2002, 124:9352. doi: 10.1021/ja027000e
23. [23]
  Evans W. J., Kozimor S. A., Ziller J. W.J. Am. Chem. Soc., 2003, 125:14264. doi: 10.1021/ja037647e
24. [24]
  Mansell S. M., Kaltsoyannis N., Arnold P. L.J. Am. Chem.Soc., 2011, 133:9036. doi: 10.1021/ja2019492
25. [25]
  Khodakov A. Y., Chu W., Fongarland P.Chem. Rev., 2007, 107:1692. doi: 10.1021/cr050972v
26. [26]
  Brennan J. G., Andersen R. A., Robbins J. L.J. Am. Chem. Soc., 1986, 108:335. doi: 10.1021/ja00262a046
27. [27]
  Parry J., Carmona E., Coles S., Hursthouse M. J.Am. Chem. Soc., 1995, 117:2649. doi: 10.1021/ja00114a030
28. [28]
  Castro-Rodriguez I., Meyer K. J.Am. Chem. Soc., 2005, 127:11242. doi: 10.1021/ja053497r
29. [29]
  Summerscales O. T., Cloke F. G. N., Hitchcock P. B., Green J. C., Hazari N.Science, 2006, 311:829. doi: 10.1126/science.1121784
30. [30]
  Summerscales O. T., Cloke F. G. N., Hitchcock P. B., Green J. C., Hazari N. J.Am. Chem. Soc., 2006, 128:9602. doi: 10.1021/ja063222r
31. [31]
  Arnold P. L., Turner Z. R., Bellabarba R. M., Tooze R. P.Chem. Sci., 2011, 2:77. doi: 10.1039/C0SC00452A
32. [32]
  Gardner B. M., Stewart J. C., Davis A. L., McMaster L. W., Blake A. J., Liddle S. T.Proc. Natl. Acad. Sci., 2012, 109:9265. doi: 10.1073/pnas.1203417109
33. [33]
  Gibson D. H.Chem. Rev., 1996, 96:2063. doi: 10.1021/cr940212c
34. [34]
  Fujita E.Coord. Chem. Rev. 1999, 185-6, 373.
35. [35]
  Keith D. W.Science, 2009, 325:1654. doi: 10.1126/science.1175680
36. [36]
  Solomon S., Plattner G. K., Knutti R., Friedlingstein P.Proc. Natl. Acad. Sci., 2009, 106:1704. doi: 10.1073/pnas.0812721106
37. [37]
  Natrajan L., Pecaut J., Mazzanti M.Dalton Trans. 2006, 1002.
38. [38]
  Andrews P. C., Beck T., Forsyth C. M., Fraser B. H., Junk P. C., Massi M., Roesky P. W.Dalton Trans. 2007, 5651.
39. [39]
  Castro-Rodriguez I., Nakai H., Zakharov L. N., Rheingold A. L., Meyer K.Science, 2004, 305:1757. doi: 10.1126/science.1102602
40. [40]
  Lam O. P., Bart S. C., Kameo H., Heinemann F. W., Meyer K.Chem. Commun., 2010, 46:3137. doi: 10.1039/b927142b
41. [41]
  Castro L., Lam O. P., Bart S. C., Meyer K., Maron L.Organometallics, 2010, 29:5504. doi: 10.1021/om100479r
42. [42]
  Schmidt A. C., Nizovtsev A. V., Scheurer A., Heinemann F. W., Meyer K.Chem. Commun., 2012, 48:8634. doi: 10.1039/c2cc34150f
43. [43]
  Matson E. M., Forrest W. P., Fanwick P. E., Bart S. C.J. Am. Chem. Soc., 2011, 133:4948. doi: 10.1021/ja110158s
44. [44]
  Kahan R. J., Cloke F. G. N., Roea S. M., Niefb F.New J. Chem., 2015, 39:7602. doi: 10.1039/C5NJ00590F
45. [45]
  Zhang S. D., Ding Y. Q., Gu Z. M., Wang X. Y., Ye G. A., Wang X. L., Shen X. H., Qin Z., Zhao Y. L., Shi Q. L., Li J. Y.Chemistry Online, 2014, 77:660.
46. [46]
  Xiao H., Hu H. S., Schwarz W. H. E., Li J. J.Phys. Chem. A, 2010, 114:8837. doi: 10.1021/jp102107n
47. [47]
  Wang Y. L., Liu Z. Y., Li Y. X., Bai Z. L., Liu W., Wang Y. X., Xu X. M., Xiao C. L., Sheng D. P., Diwu J., Su J., Chai, Z.F.; Albrecht-Schmitt T. E., Wang S. A.J. Am. Chem. Soc., 2015, 137:6144. doi: 10.1021/jacs.5b02480
48. [48]
  Liu W. J.Mol. Phys., 2010, 108:1679. doi: 10.1080/00268971003781571
49. [49]
  Hu S. W., Wang X. Y., Chu T. W., Liu X. Q.J. Phys. Chem. A, 2009, 113:9243. doi: 10.1021/jp904655w
50. [50]
  Zhang L., Hou G. H., Zi G. F., Ding W. J., Walter M. D.J. Am. Chem. Soc., 2016, 138:5130. doi: 10.1021/jacs.6b01391
51. [51]
  Ding W. J., Fang W. H., Chai Z. F., Wang D. Q.J. Chem. Theory Comput., 2012, 8:3605. doi: 10.1021/ct300075n
52. [52]
  Ding W. J., Wang D. Q.Organometallics, 2014, 33:7007. doi: 10.1021/om500797h
53. [53]
  Wang D.-Q., Gunsteren W. F.V. Prog. Chem., 2011, 23:1566.
1. [1]
  Ming Li , Zhaoyin Li , Mengzhu Liu , Shaoxiang Luo . Unveiling the Artistry of Mordant Dyeing: The Coordination Chemistry Beneath. University Chemistry, 2024, 39(5): 258-265. doi: 10.3866/PKU.DXHX202311085
2. [2]
  Chengtian Liang , Boyuan Zheng , Ning Fang . 第38届中国化学奥林匹克(初赛)配位化学试题解析. University Chemistry, 2025, 40(8): 394-400. doi: 10.12461/PKU.DXHX202410054
3. [3]
  Zhe Ji , Guangxu Lan , Jiangnan Li , Sihai Yang . A New Protocol to Construct Molecular Materials: A Brief Introduction on the 2025 Nobel Prize in Chemistry. University Chemistry, 2025, 40(12): 70-77. doi: 10.12461/PKU.DXHX202511097
4. [4]
  Keweiyang Zhang , Zihan Fan , Liyuan Xiao , Haitao Long , Jing Jing . Unveiling Crystal Field Theory: Preparation, Characterization, and Performance Assessment of Nickel Macrocyclic Complexes. University Chemistry, 2024, 39(5): 163-171. doi: 10.3866/PKU.DXHX202310084
5. [5]
  Quanguo Zhai , Peng Zhang , Wenyu Yuan , Ying Wang , Shu'ni Li , Mancheng Hu , Shengli Gao . Reconstructing the “Fundamentals of Coordination Chemistry” in Inorganic Chemistry Course. University Chemistry, 2024, 39(11): 117-130. doi: 10.12461/PKU.DXHX202403065
6. [6]
  Qinglin Yang , Yonghai Yue , Kesong Liu , Lidong Li , Tianyi Zhao , Wei Zhou , Dongyu Zhao , Yuzhen Ning . Teaching design and practice in analytical chemistry based on “graphic teaching method + problem-based learning”: taking coordination titration as an example. University Chemistry, 2026, 41(6): 84-91. doi: 10.12461/PKU.DXHX202510004
7. [7]
  Zhao Feifan , Xu Feiyan , Yu Jiaguo . Interfacial stabilization of alkali metal oxides on carbon spheres for high-performance CO₂ chemisorption. Acta Physico-Chimica Sinica, 2026, 42(5): 100234-. doi: 10.1016/j.actphy.2025.100234
8. [8]
  Xiuhong Liu , Cunxu Yan , Yue Zhang , Xuesong Gao , Haifeng He . 一种新型荧光指示剂应用于配位滴定法中铜含量的测定——分析化学实验教学设计与实践. University Chemistry, 2026, 41(8): 389-401. doi: 10.12461/PKU.DXHX202507135
9. [9]
  Huifang XIAO , Xiaoqian HU , Xiaofan YE , Lihui LIU , Fen NIE , Yanrong DING , Ying MA , Yanzhu LIU , Yongxiu LI . Coordination-enhanced leaching of bastnaesite from mixed rare earth concentrates and comprehensive recycling of valuable elements. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 141-151. doi: 10.11862/CJIC.20250049
10. [10]
  Wenke ZHENG , Ce LIU , Wei CHEN , Hongshan KE , Fanlong ZENG , Yibo LEI , Anyang LI , Wenyuan WANG . Synthesis and bonding analysis of low-coordinate Fe and Cr complexes with ultra-bulky silylamino groups. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1285-1293. doi: 10.11862/CJIC.20250095
11. [11]
  Dong Xiang , Kunzhen Li , Kanghua Miao , Ran Long , Yujie Xiong , Xiongwu Kang . Amine-Functionalized Copper Catalysts: Hydrogen Bonding Mediated Electrochemical CO₂ Reduction to C₂ Products and Superior Rechargeable Zn-CO₂ Battery Performance. Acta Physico-Chimica Sinica, 2024, 40(8): 2308027-0. doi: 10.3866/PKU.WHXB202308027
12. [12]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . Electrochemical CO₂ Reduction to C₂₊ Products with Ampere-Level Current on Carbon-Modified Copper Catalysts. Acta Physico-Chimica Sinica, 2025, 41(3): 100024-0. doi: 10.3866/PKU.WHXB202404012
13. [13]
  Yajun Jian , Quan Gu , Quanguo Zhai . Chemistry Frontiers-Intelligent Educational Technologies Collaborate to Construct CO₂ Teaching Units. University Chemistry, 2026, 41(2): 82-94. doi: 10.12461/PKU.DXHX202503014
14. [14]
  Yongmin Zhang , Shuang Guo , Yue Zhou . CO₂刺激响应型微乳液的构建及应用——一个化学综合实验的设计与实践. University Chemistry, 2026, 41(8): 363-369. doi: 10.12461/PKU.DXHX202507069
15. [15]
  Yongqing Xu , Yuyao Yang , Mengna Wu , Xiaoxiao Yang , Xuan Bie , Shiyu Zhang , Qinghai Li , Yanguo Zhang , Chenwei Zhang , Robert E. Przekop , Bogna Sztorch , Dariusz Brzakalski , Hui Zhou . Review on Using Molybdenum Carbides for the Thermal Catalysis of CO₂ Hydrogenation to Produce High-Value-Added Chemicals and Fuels. Acta Physico-Chimica Sinica, 2024, 40(4): 2304003-0. doi: 10.3866/PKU.WHXB202304003
16. [16]
  Beibei Gao , Lipeng Zhou , Dexin Yang . Integrating the “Dual Carbon” Concept into Teaching Reform of Physical Chemistry: A Case of CO₂ Hydrogenation to CH₃OH. University Chemistry, 2026, 41(3): 248-253. doi: 10.12461/PKU.DXHX202504011
17. [17]
  Dan Li , Dexin Yang . Innovative Practice in Physical Chemistry Curriculum Based on the “Dual Carbon” Goals: A Case of Metal-CO₂ Batteries. University Chemistry, 2026, 41(3): 268-273. doi: 10.12461/PKU.DXHX202504014
18. [18]
  Wenjiao Xiao , Yangyang Cheng , Haiying Jiang . 碳中和背景下的CO₂还原——第57届国际化学奥林匹克试题第6题解析. University Chemistry, 2026, 41(8): 459-468. doi: 10.12461/PKU.DXHX202511209
19. [19]
  Chen Hu , Yu Wu , Lianqing Chen , Tao Huang , Chunya Li , Lin Li , Bingguang Zhang , Peng Mei . 基于“三位一体四融合”策略的化学实验室安全课程创新与探索. University Chemistry, 2025, 40(8): 25-32. doi: 10.12461/PKU.DXHX202410088
20. [20]
  Zengyong Chu , Tianjiao Hu , Zhenhua Jiang , Xiaojie Wang , Ye Zhang , Xiaodong Li . Trinity and four-dimensional synergy: construction and practice of a model ideological-political course in “chemical principles of military high technology”. University Chemistry, 2026, 41(7): 76-84. doi: 10.12461/PKU.DXHX202506091

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(4482)
HTML views(990)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142