Citation: Chen Jinping, Du Xinfeng, Yu Tianjun, Zeng Yi, Zhang Xiaohui, Li Yi. Ligand Substituent Effects on Rhenium Tricarbonyl Catalysts in CO₂ Reduction[J]. Acta Chimica Sinica, ;2016, 74(6): 523-528. doi: 10.6023/A16010067 shu

Ligand Substituent Effects on Rhenium Tricarbonyl Catalysts in CO₂ Reduction

1.
Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190

Corresponding author: Chen Jinping, chenjp@mail.ipc.ac.cn Li Yi, yili@mail.ipc.ac.cn
Received Date: 29 January 2016

Fund Project: the National Natural Science Foundation of China 21233011the National Natural Science Foundation of China 21472201the National Basic Research Program 2013CB834505the National Natural Science Foundation of China 21573266the National Basic Research Program 2013CB834700

Figures(7)

The Re (I) complexes originally reported by Lehn et al. is one of the most important catalysts used for photocatalytical reduction of CO₂ in homogeneous system. The mechanism for the photocatalytic reduction of CO₂ to CO with Re (I) complexes has been thoroughly investigated recently. In this study, a series of rhenium tricarbonyl catalysts (Re-Me, Re-Ac, Re-Qa and Re-Im) with different substituents on 2, 2-bipyridine ligand were synthesized and characterized. These catalysts were successfully applied to a light induced CO₂ reduction system with triethanolamine (TEOA) as sacrificial reagent, exhibiting different turnover numbers for different catalysts. The highest turnover number was achieved for the catalyst of Re-Qa, and Re-Me and Re-Ac exhibit similar activity, while Re-Im exhibits almost no activity in the photocatalytic conversion of CO₂ to CO. UV-vis spectra show that the rate of deactivation is linked to the decomposition of the catalysts in the photocatalytic system. No decomposition was observed in the absence of TEOA, suggesting that the deactivation occurs via the intermediate of one-electron-reduced (OER) species. The transient absorption spectra conformed the formation of OER in the catalytic system. The reasons for the highest turnover number of Re-Qa may be attributed to the quaternary ammonium salt group, which can serve as a mediator to facilitate the reduction process. While in the case of Re-Im, the imidazolium group might accelerate the deactivation of OER species by an intramolecular interaction. Further experiments on this effect are the subject of ongoing investigations.
- homogeneous photocatalysis,
- CO₂ reduction,
- rhenium (I) complex,
- ligand effect,
- deactivation
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Ligand Substituent Effects on Rhenium Tricarbonyl Catalysts in CO₂ Reduction