Citation: SUN Yue, ZHANG Xian-Hui, NA Yan-Xiang, LI Chang-Li, FENG Ke-Cheng. Construction of Organic-Inorganic Hybrid from Dawson-Type Tungstophosphate and Tetranuclear Copper Complex[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2568-2574. doi: 10.3969/j.issn.1001-4861.2013.00.401 shu

Construction of Organic-Inorganic Hybrid from Dawson-Type Tungstophosphate and Tetranuclear Copper Complex

1.
1 School of science, Changchun University of Science and Technology, Changchun 130022, China;

Received Date: 16 July 2012
Available Online: 6 June 2013

A novel hybrid compound [CuCl(H₂O)₄)][CuCl(H₂O)(Phen)][{(CuPhen)₂Cl₂}₂(bdc)]₂[P₂W₁₈O₆₂]·5H₂O(1) (Phen=1,10-phenanthroline and bdc=1,4-benzenedicarboxylate), containing multinuclear Cu^Ⅱ complex cations, has been obtained in hydrothermal conditions and characterized by IR, elemental, thermogravimetric, electrochemical and single-crystal X-ray diffraction analysis. The main structural feature to this compound is the copper-Phen complex moieties which compose new tetranuclear copper-Phen complex cation [{(CuPhen)₂Cl₂}₂(bdc)]²⁺ bridged by Cl and bdc ligands. Furthermore, a Compound 1-modiffied carbon paste electrode (1-CPE) displays the good electrocatalytic activity toward the reduction of nitrite. CCDC: 952036.
- organic-inorganic hybrid;dawson-type POM;tetranuclear copper complex;1,4-bdc linkage;electrocatalytic property
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沈阳化工大学材料科学与工程学院沈阳 110142