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Citation: YAN Zhi-Ying, LI Jun-Jie, DUAN De-Liang, WANG Wei, WANG Jia-Qiang. Ionic Liquid-Assisted Hydrothermal Synthesis of Hexagonal WO3 Nanorod Bundles[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2637-2642. doi: 10.3969/j.issn.1001-4861.2013.00.397 shu

Ionic Liquid-Assisted Hydrothermal Synthesis of Hexagonal WO3 Nanorod Bundles

  • 1.

    School of Chemical Science and Engineering, Yunnan University, Kunming 650091, China

  • Received Date: 14 June 2013
    Available Online: 1 September 2013

    Fund Project: 国家自然科学基金(No.21063016，No.U1033603)资助项目。 (No.21063016，No.U1033603)

  • Hexagonal tungsten oxide (h-WO3) was synthesized by an ionic liquid (1-methyl-3-ethyl imidazole bromide (Emim+Br-)) -assisted hydrothermal method at 180 ℃ for 21 h. The as-synthesized products were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM) and energy dispersive X-ray spectroscopy (EDS). The results show that the morphologies of WO3 are controlled by the amount of Emim+Br-. In 0.5 g Emim+Br--added solution, the product is h-WO3 nanorod bundles composed of uniform WO3 nanorods with average diameter of 25 nm and length of 200~300 nm. The formation mechanism of h-WO3 nanorod bundles is proposed according to the experimental results.
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    1. [1]

      [1] Xia Y, Yang P, Sun Y, et al. Adv. Mater., 2003, 15 (5): 353-389

    2. [2]

      [2] Chen D, Ye J H. Adv. Funct. Mater., 2008, 18:1922-1927

    3. [3]

      [3] Hibino M, Han W, Kudo T. Solid State Ionics, 2000, 135 (1/3/ 4):61-69

    4. [4]

      [4] Wang S J, Lu W J, Cheng G, et al. Appl. Phys. Lett., 2009, 94 (26):263106-263109

    5. [5]

      [5] Wu Y, Xi Z H, Zhang G M, et al. J. Cryst. Growth, 2006, 292:143-148

    6. [6]

      [6] Gu Z J, Ma Y, Yang W S, et al. Chem. Commun., 2005, 5 (28):3597-3599

    7. [7]

      [7] CHENG Li-Fang (程利芳), ZHANG Xin-Tang (张兴堂), CHEN Yan-Hui (陈艳辉), et al. Chinese. J. Inorg. Chem. (Wuji Huaxue Xuebao), 2004, 20 (9):1117-1122

    8. [8]

      [8] Gu Z J, Li H Q, Zhai T Y, et al. J. Solid State Chem., 2007, 180:98-105

    9. [9]

      [9] Gu Z J, Zhai T Y, Gao B F, et al. J. Phys. Chem. B, 2006, 110:23829-23836

    10. [10]

      [10] Phuruangrat A, Ham D J, Hong S J, et al. J. Mater. Chem., 2010, 20:1683-1690

    11. [11]

      [11] Ha J H, Muralidharan P, Kim D K. J. Alloys Compd., 2009, 475:446-451

    12. [12]

      [12] Zhang J, Tu J P, Xia X H, et al. J. Mater. Chem., 2011, 21: 5492-5498

    13. [13]

      [13] Peng T Y, Ke D N, Xiao J R, et al. J. Solid State Chem., 2012, 194:250-256

    14. [14]

      [14] Lou X W, Zeng H C. Inorg. Chem., 2003, 42 (20):6169-6171

    15. [15]

      [15] Wang J M, Khoo E, Lee P S, et al. J. Phys. Chem. C, 2008, 112:14306-14312

    16. [16]

      [16] Salmaoui S, Sediri F, Gharbi N. Polyhedron, 2010, 29:1771-1775

    17. [17]

      [17] Tong P V, Hoa N D, Quang V V. Sens. Actuators B, 2013, 183:372-380

    18. [18]

      [18] Biswas K, Rao C N R. Chem. Eur. J., 2007, 13 (21):6123-6129

    19. [19]

      [19] Yang L X, Zhu Y J, Wang W W, et al. J. Phys. Chem. B, 2006, 110 (13):6609-6614

    20. [20]

      [20] Shang Y, Hong J, Liu L. et al. J. Solid State Chem., 2010, 183 (3):696-701

    21. [21]

      [21] Liu X, Ma J, Zheng W. Rev. Adv. Mater. Sci., 2011, 27:43-51

    22. [22]

      [22] Lian J B, Kim T I, Liu X D, et al. J. Phys. Chem. C, 2009, 113 (21):9135-9140

    23. [23]

      [23] Zheng W J, Liu X D, Yan Z Y, et al. ACS Nano, 2009, 3 (1): 115-122

    24. [24]

      [24] Zhang J, Huang F, Zhang L. Nanoscale, 2010, 2:18-34

    25. [25]

      [25] Zitoun D, Pinna N, Frolet N, et al. J. Am. Chem. Soc., 2005, 127:15034-15035

    26. [26]

      [26] Chang H C, Jiang J C, Tsai W C, et al. Chem. Phys. Lett., 2006, 427 (4/5/6):310-316

  • 加载中
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