Citation: ZHANG Jian-Guo, YIN Xin, WU Jin-Ting, SUN Mou, FENG Jin-Ling, ZHANG Tong-Lai, ZHOU Zun-Ning. Two High-Nitrogen Energetic Salts Based on 3,6-Dihydrazino-1,2,4,5-tetrazine[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2587-2594. doi: 10.3969/j.issn.1001-4861.2013.00.391 shu

Two High-Nitrogen Energetic Salts Based on 3,6-Dihydrazino-1,2,4,5-tetrazine

1.
State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China

Received Date: 22 April 2013
Available Online: 29 August 2013
Fund Project: 国家自然科学基金项目(No.10776002)，爆炸科学与技术国家重点实验室自主课题(No.ZDKT12-03) (No.10776002)，爆炸科学与技术国家重点实验室自主课题(No.ZDKT12-03)教育部新世纪优秀人才支持计划(No.NCET-09-0051)资助项目。 (No.NCET-09-0051)

Two high-nitrogen energetic salts were prepared by reacting 3,6-dihydrazino-1,2,4,5-tetrazine (DHT) and perchloric acid or nitric acid aqueous solution. Their structures have been determined by using X-ray single crystal diffraction method. (DHT)(NO₃)₂ (1) belongs to monoclinic, C2/c space group, a=1.300 0(6) nm, b= 0.834 9(3) nm, c=1.018 7(5) nm, β=118.89(5)°, Z=4; (DHT)(ClO₄)₂(2) belongs to orthorhombic, P2₁2₁2 space group, a=0.980 4(4) nm, b=1.074 7(4) nm, c=0.532 5(2) nm, Z=2. The thermal decomposition was investigated with DSC and TG-DTG measurement. The non-isothermal kinetic parameters of the first exothermic process were studied by applying Kissingers, Ozawa-Doyles and Starinks methods. The critical temperature of thermal explosion and sensitivity properties also have been fully investigated. We can come to the conclusion that the two salts have potential application in sensitive energetic material area. CCDC: 884111, 1; 884112, 2.
- crystal structure;energetic ionic salts;3,6-dihydrazino-1,2,4,5-tetrazine;thermal decomposition;sensitivity
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沈阳化工大学材料科学与工程学院沈阳 110142