Citation: ZHOU Ben-Hua, CAI Jin, JI Min. Crystal Structure and Dielectric Property of a One-Dimentional Compound (C₂H₈N)[Hg₂Cl₅][J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2709-2713. doi: 10.3969/j.issn.1001-4861.2013.00.372 shu

Crystal Structure and Dielectric Property of a One-Dimentional Compound (C₂H₈N)[Hg₂Cl₅]

1.
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

Received Date: 2 April 2013
Available Online: 4 July 2013
Fund Project: 国家重点基础研究发展计划(No.2011CB933500，No.2011CB933503) (No.2011CB933500，No.2011CB933503)江苏省科技支撑计划(No.BE2009639，BE2012657)资助项目。 (No.BE2009639，BE2012657)

Reaction of dimethylammonium chloride with mercuric chloride in aqueous solution yielded one novel organic-inorganic hybrid compound (C₂H₈N)[Hg₂Cl₅](1). X-ray structure determination reveals that complex 1 shows a one-dimensional chloride-bridged [Hg₂Cl₅]_n anionic chain structure along the b axis. Each Hg(Ⅱ) ion is coordinated with four chloride ions. Temperature-dependent dielectric constant of 1 shows no distinct anomalies, suggesting no phase transition occurred in the measured temperature range 80~298 K. CCDC: 880350.
- Hg(Ⅱ) complex;dimethylamine;crystal structure;dielectric constant
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

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Crystal Structure and Dielectric Property of a One-Dimentional Compound (C₂H₈N)[Hg₂Cl₅]