Citation: DENG Yi-Fang, CHEN Man-Sheng, ZHANG Chun-Hua, KUANG Dai-Zhi, NIE Xue, YANG Ying-Qun, LI Wei. Synthesis, Crystal Structure and Photoluminescent Property of Zn(Ⅱ) Complex Constructed from 1,3-Benzenedicarboxylate and 1,4-Di(1-imidazoly)benzene[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2195-2199. doi: 10.3969/j.issn.1001-4861.2013.00.365 shu

Synthesis, Crystal Structure and Photoluminescent Property of Zn(Ⅱ) Complex Constructed from 1,3-Benzenedicarboxylate and 1,4-Di(1-imidazoly)benzene

1.
1 Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Chinese Ministry of Education, Jilin Normal University, Siping, Jilin 136000, China;

Received Date: 8 May 2013
Available Online: 9 June 2013
Fund Project: 湖南省自然科学基金(No.13JJ6069) (No.13JJ6069)湖南省教育厅创新平台开放基金(No.11K009) (No.11K009)

Anew 2D Zn(Ⅱ) metal-organic framework, [Zn₂(dib)(1,3-BDC)₂(H₂O)] (1), has been synthesized by the hydrothermal reaction of 1,3-benzenedicarboxylate with ZnSO₄·7H₂Oin the presence of 1,4-di(1-imidazoly)benzene (dib=1,4-di(1-imidazoly)benzene, 1,3-H₂BDC=1,3-benzenedicarboxylate). The crystal is of monoclinic system, space group P2₁/n, with a=0.80367(12) nm, b=1.3327(2) nm, c=2.3725(4) nm, β=97.394(3)°, V=2.5199(7) nm³, Z=4, F(000)=1392, R=0.0520 and wR=0.0994 (I>2σ(I)). The two central zinc(Ⅱ) ions in the complex locate in a different coordination geometry, one is a distorted tetrahedral and the other is a distorted square-pyramidal coordination geometry, respectively. The dib ligand acts as a bridging ligand, which links the 1D double-chain into 2D layer structure. The net is linked into three-dimensional supramolecular network by O-H…Ohydrogen bonds. CCDC: 895702.
- hydrothermal synthesis; zinc(Ⅱ) complex; crystal structure; luminescence property
1. [1]
  [1] O'Keeffe M, Yaghi O M. Chem. Rev., 2012,112:675-702 [2] Stock N, Biswas S. Chem. Rev., 2012,112:933-969 [3] Cui Y J, Yue Y F, Qian G D, et al. Chem. Rev., 2012,112: 1126-1162 [4] Cohen S M. Chem. Rev., 2012,112:970-1000 [5] Ouellette W, Jones S, Zubieta J. CrystEngComm, 2011,13: 4457-4485 [6] Liu Y Y, Wang Z H, Yang J, et al. CrystEngComm, 2011,13: 3811-3821 [7] Chen S S, Bai Z S, Fan J, et al. CrystEngComm, 2010,12: 3091-3104 [8] Guo Z G, Cao R, Li X J, et al. Eur. J. Inorg. Chem., 2007: 742-748 [9] Liu T F, Lu J, Shi L X, et al. CrystEngComm, 2009,11:583- 588 [10]Geng X H, Feng Y L, Lan Y Z. Inorg. Chem. Commun., 2009,12:447-449 [11]Lu Y, Lan Y Q, Xu Y H, et al. J. Solid State Chem., 2009, 182:3105-3112 [12]Withersby M A, Blake A J, Champness N R, et al. J. Am. Chem. Soc., 2000,122:4044-4046 [13]Liu G X. Chinese J. Struct. Chem., 2012,31:933-938 [14]Sheldrick G M. SHELXL-97, Programm for the Refinement of Crystal Structure, University of G?觟ttingen G?觟ttingen, 1997. [15]CHEN Zhi-Min(陈志敏), KUANG Dai-Zhi (邝代治), FENG Yong-Lan (冯泳兰), et al. Chemistry(Huaxue Tongbao), 2005,68:http://www.hxtb.org/col/2005/pdf/c05081.pdf [16]Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. 5th Ed.. New York: John Wiley & Sons, 1997. [17]Vogler A, Kunkely H. Coord. Chem. Rev., 2006,250:1622- 1626 [18]Yang W Y, Schmider H, Wu Q G., et al. Inorg. Chem., 2000,39:2397-2404
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沈阳化工大学材料科学与工程学院沈阳 110142