Citation: CHEN Xiao-Li, QIAO Ya-Li, GAO Lou-Jun, LÜ Jun-Fang, CUI Hua-Li. Structural and Spectral Study of Terbium 4-Hydroxypyridine-2, 6-Dicarboxylic Acid Coordination Polymer[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2357-2362. doi: 10.3969/j.issn.1001-4861.2013.00.363 shu

Structural and Spectral Study of Terbium 4-Hydroxypyridine-2, 6-Dicarboxylic Acid Coordination Polymer

1.
Shaanxi Key Laboratory of Chemical Reaction Engineering, Department of Chemistry and Chemical Engineering, Yanan University, Yan'an, Shaanxi 716000, China

Received Date: 25 February 2013
Available Online: 25 June 2013
Fund Project: 国家自然科学基金(No.21101133) (No.21101133)陕西省教育厅专项科研基金(No.11JK0565)资助项目。 (No.11JK0565)

A 2D Tb^Ⅲ coordination polymer [Tb(cam)(H₂O)₃]_n·nH₂O (1) (H₃cam=4-Hydroxypyridine-2,6-dicarbo-xylic acid) was synthesized under hydrothermal conditions and characterized by elemental analysis, IR spectrum, single-crystal X-ray diffraction, UV-Vis, Fluorescence, TGA and XRD. The Tb^Ⅲ ion is eight-coordinate with a slightly distorted dodecahedron geometry. One Tb^Ⅲ ion joined with three (cam)^3- ions to form a 2D layered with (4·8²) topological. The neighboring layers are linked into 3D supramolecular network through hydrogen bonding interaction. The luminescence experiments show that 1 exhibits typical Tb^Ⅲ-centered emissions in the solid state, the energy level difference was well matched and the emission of terbium complex was characteristic and high. CCDC: 922429.
- terbium coordination polymer;crystal structure;hydrothermal synthesis;spectral analysis
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沈阳化工大学材料科学与工程学院沈阳 110142