Citation: XU Fu-Qiu, CHEN Hua-Jun, DING Wu-Xiu. Preparation and Antibacterial Property of Ag-Doped Hydroxyapatite Antibacterial Powders and Antibacterial Ceramic[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2582-2586. doi: 10.3969/j.issn.1001-4861.2013.00.362 shu

Preparation and Antibacterial Property of Ag-Doped Hydroxyapatite Antibacterial Powders and Antibacterial Ceramic

1.
Department of Environment and Chemistry, Luoyang Institute of Science and Technology, Luoyang, Henan 471023, China

Received Date: 4 January 2013
Available Online: 26 May 2013
Fund Project: 国家自然科学基金(No.51279073) (No.51279073)河南省科技攻关课题(No.132102310367)资助项目。 (No.132102310367)

Silver doped hydroxyapatite antimicrobial powders were synthesized by one-step reaction, then it was used for preparing antibacterial ceramic. The experimental results show that there was a significant linear correlation between silver content of HA and quantity of silver nitrate at hydrothermal condition. The XRD patterns and TEM photos indicate that HA and Ag-HA have the same crystal structure, and Ca²⁺ in HA crystals is displaced by Ag⁺ and Ag_xCa_1-x(PO₄)₆(OH)₂ was produced at hydrothermal condition. The length of Ag-HA antimicrobial powders increases with the increase of content of Ag⁺ in Ag-HA. Ag-HA antimicrobial powders went from sticks to whisker when the contents of Ag⁺ in Ag-HA exceeds 1.5%. 4.50% Ag-HA was selected as antimicrobial powders, an antibacterial rate of antibacterial ceramic is above 99.9%. and at this point, the mass fraction of Ag₃PO₄ in antimicrobial tglazes is 0.56%, which was far below 2wt%~4wt% of Ag₃PO₄ in antimicrobial tglazes of ongoing research. This technology can not only reduce the cost of producing antibacterial ceramic, but also meet JC/T 897-2002 demands for antibacterial properties of antibacterial ceramic.
- Ag;hydroxyapatite(HA);hydro-thermal method;antibacterial property;ceramic
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沈阳化工大学材料科学与工程学院沈阳 110142