Citation: HAO Jin-Ming, LI Huan-Huan, LI Guang-Yue, CUI Guang-Hua. Two Dimensional Cadmium (Ⅱ) Coordination Polymer Constructed from Flexible Bis(triazole) Ligand：Synthesis, Structure and Fluorescence Property[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2450-2454. doi: 10.3969/j.issn.1001-4861.2013.00.361 shu

Two Dimensional Cadmium (Ⅱ) Coordination Polymer Constructed from Flexible Bis(triazole) Ligand：Synthesis, Structure and Fluorescence Property

1.
College of Chemical Engineering, Hebei United University, Tangshan, Hebei 063009, China

Received Date: 28 January 2013
Available Online: 9 June 2013
Fund Project: 国家自然科学基金(No.11247281) (No.11247281)河北省教育厅优秀青年基金(No.Y2012010)资助项目 (No.Y2012010)

The new coordination polymer named, {[Cd(L)(HBTC)(H₂O)]·H₂O}_n (L=1,2-bis(1,2,4-triazol-1-ylmethyl)benzene, H₃BTC=1,3,5-benzenetricarboxylic acid) has been synthesized hydrothermally and characterized by elemental analysis, IR spectroscopy, thermogravimetric (TG) analysis and single-crystal X-ray diffraction analysis. The cadmium center is six coordinated with three OCOO-atoms from two different HBTC^2- dianions and one water molecule locate in the equatorial positions, while apical sites are occupied by two Natoms from two distinct Lligands in a distorted octahedral geometry. The structural analysis shows that the complex possesses a two-dimensional 2D (4,4) layer structure, and displays a three-dimensional (3D) supramolecular structure via multiple intermolecular O-H…O hydrogen bonds. The fluorescence property of the complex also has been studied. CCDC: 917952.
- cadmium(Ⅱ) complex;crystal structure;fluorescence property;(4, 4) network
1. [1]
  [1] Guillem A, Leoní A B, Olivier R, et al. Coord. Chem. Rev., 2011,255:485-546
2. [2]
  [2] Jing W, Ren Z G, Lang J P, et al. CrystEngComm, 2011,13 (16):5111-5118
3. [3]
  [3] Hunger J, Krautscheid H, Sieler J. Cryst. Growth Des., 2009, 9(11):4613-4625
4. [4]
  [4] Zhang Y B, Zhang W X, Feng F Y, et al. Angew. Chem., 2009,121(29):5391-5394
5. [5]
  [5] LIU Tong-Fei(刘同飞), CUI Guang-Hua(崔广华), JIAO Cui-Huan(焦翠欢), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(7):1417-1422
6. [6]
  [6] Yang J, Ma J F, Liu Y Y, et al. Inorg. Chem., 2007,46(16): 6542-6555
7. [7]
  [7] Chu Q, Su Z, Fan J, et al. Cryst. Growth Des., 2011,11(9): 3885-3894
8. [8]
  [8] Ding B, Yi L, Gao H L, et al. Inorg. Chem. Commun., 2005, 8(1):102-104
9. [9]
  [9] Effendy F, Marchetti C, Pettinari R, et al. Inorg. Chem., 2003,42(4):112-117
10. [10]
  [10]Zhao Q H, Li H F, Wang X F, et al. New J. Chem., 2002,26 (12):1709-1710
11. [11]
  [11]Cui G H, He C H, Jiao C H, et al. CrystEngComm, 2012,14: 4210-4216
12. [12]
  [12]Zhu X, Ge H Y, Zhang Y M, et al. Polyhedron, 2006,25(9): 1875-1883
13. [13]
  [13]Fan J, Sun W Y, Okamura T, et al. Cryst. Growth Des., 2004,4(3):579-584
14. [14]
  [14]Platers M J, Howie R A, Roberts A. J. Chem. Commun., 1997,9:893-897
15. [15]
  [15]Chen W, Wang J Y, Chen C, et al. Inorg. Chem., 2003,42 (4):944-946
16. [16]
  [16]Du J L, Hu T, Zhang S M, et al. CrystEngComm, 2008,10: 1866-1874
17. [17]
  [17]Sheldrick G M. Acta Cryst., 2008,A64:112-122
18. [18]
  [18]Deacon G B, Phillips R J. Coord. Chem. Rev., 1980,33:227-250
19. [19]
  [19]GENG Xiao-Hong(耿晓红), FENG Yun-Long(冯云龙). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(2): 360-364
20. [20]
  [20]Yuan W B, Liu T F, Guo Z G, et al. J. Mol. Struct., 2010, 965(1-3):82-88
1. [1]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
2. [2]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
3. [3]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
4. [4]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
5. [5]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
6. [6]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
7. [7]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
8. [8]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
9. [9]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
10. [10]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
11. [11]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
12. [12]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
13. [13]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
14. [14]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
15. [15]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
16. [16]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
17. [17]
  Linjie ZHU , Xufeng LIU . Synthesis, characterization and electrocatalytic hydrogen evolution of two di-iron complexes containing a phosphine ligand with a pendant amine. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 939-947. doi: 10.11862/CJIC.20240416
18. [18]
  Ruiying WANG , Hui WANG , Fenglan CHAI , Zhinan ZUO , Benlai WU . Three-dimensional homochiral Eu(Ⅲ) coordination polymer and its amino acid configuration recognition. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 877-884. doi: 10.11862/CJIC.20250052
19. [19]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
20. [20]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(557)
HTML views(27)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142