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Citation: HUANG Bin, CHEN Yun-Cong, GUO Zi-Jian, HE Wei-Jiang. A New Sensitive Fluorescent H2S Probe Based on Cu2+ Complex[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2283-2288. doi: 10.3969/j.issn.1001-4861.2013.00.347 shu

A New Sensitive Fluorescent H2S Probe Based on Cu2+ Complex

  • 1.

    State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093 China

  • Received Date: 16 May 2012
    Available Online: 6 May 2013

    Fund Project: 国家自然科学基金(No.21271100) (No.21271100)重大基础研究计划(No.2011CB935800)资助项目。 (No.2011CB935800)

  • As the third gasotransmitter after NOand CO, hydrogen sulfide plays essential biological roles in living systems, and developing sensitive fluorescent probe for the rapid tracking of endogenous H2S is attracting much attention. Anew H2S fluorescent probe was constructed in this study based on a copper complex formed by a new NBD fluorescent ligand, in which a Cu2+ chelator was incorporated. This probe displays very weak emission owing to the emission quenching effect of Cu2+, and it is able to sense H2S by exhibiting distinct emission enhancement upon H2S addition. The S2-induced Cu2+ removal from this complex was proposed as the sensing mechanism of this Cu2+ complex-based probe. Besides the quick response, the high sensing selectivity over other anion of this probe has also been confirmed, and its detection limit was estimated to be ~0.2 μmol·L-1, and the linear range is 1~20 μmol·L-1.
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