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Citation: JIANG Li-Long, LIU Xian, CAO Yan-Ning, ZENG Jie-Kai, LIN Shi-Tuan, WEI Ke-Mei. Effect of Fe2O3 Content on Structure and Catalytic Performance of Cu-Fe/Bauxite for Water Gas Shift Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2297-2304. doi: 10.3969/j.issn.1001-4861.2013.00.338 shu

Effect of Fe2O3 Content on Structure and Catalytic Performance of Cu-Fe/Bauxite for Water Gas Shift Reaction

  • 1.

    National Engineering Research Center for Chemical Fertilizer Catalyst at Fuzhou University, Fuzhou 350002, China

  • Received Date: 9 March 2013
    Available Online: 6 June 2013

    Fund Project: 福建省自然科学基金(No.2011J01036) (No.2011J01036)福州大学育苗基金(No.2012-XY-5)资助项目。 (No.2012-XY-5)

  • Using modified bauxite with large surface area and mesoporous structure as the support, a series of Cu-Fe/Bauxite catalysts were synthesized with co-precipitation method. The catalysts were characterized by means of X-ray fluorescence spectrometry (XRF), X-ray diffraction (XRD), SBET, H2-temperature-programmed reduction (H2-TPR) and CO temperature-programmed desorption (CO-TPD) and X-ray photoelectron spectroscopy (XPS). Their catalytic activity in water gas shift (WGS) reaction has also been studied. The results indicate that the WGS reaction activity increases markedly with increasing the content of supported Fe2O3 and when the content of Fe2O3 is to 20%, the catalyst exhibits the highest activity. Because there exists obvious interaction between supported Fe2O3 and CuO to form composite oxide like CuFe2O4 and it enhances with increase in Fe2O3 content. The interaction promotes the reduction of Fe2O3 and CuO and restrains the clotting of CuO, and then the catalytic activity increases.
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    1. [1]

      [1] JIANG Li-Long(江莉龙), YE Bing-Huo(叶炳火), WEI Ke-Mei(魏可镁). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2007,23(10):1733-1737

    2. [2]

      [2] FENG Shu-Bo(冯树波), LIANG Rui-E(梁瑞娥), DONG-Xian-Deng(董献登), et al. Chin. J. Catal. (Cuihua Xuebao), 1996,17:391-393

    3. [3]

      [3] Li Y, Fu Q, Flytzani-Stephanopoulos M. Appl. Catal. B, 2000, 27:179-191

    4. [4]

      [4] ZHENG Qi(郑起), XU Jian-Ben(徐建本), WEI Ke-Mei (魏可镁),et al. Chin. J. Catal. (Cuihua Xuebao), 1999,01: 21-24

    5. [5]

      [5] Zhang H M, Wu S Y, Zhang Z H. Condens. Matter. Phys., 2011,14:1-6

    6. [6]

      [6] Sagar G V, Rao P V R, Srikanth C S, et al. J. of Phys. Chem. B, 2006,110:13881-13888

    7. [7]

      [7] Chen C S, You J H., Lin J H, et al. Catal. Commun., 2008, 9:1230-1234

    8. [8]

      [8] Tanaka Y. J. Catal., 2003,215:271-278

    9. [9]

      [9] Shishido T, Yamamoto M, Atake I, et al. J. Mol. Catal. A: Chem., 2006,253:270-278

    10. [10]

      [10]Chen C S, Cheng W H, Lin S S. Appl. Catal., A, 2004,257: 97-106

    11. [11]

      [11]Lendzion-Bielun Z, Bettahar M M, Monteverdi S. Catal. Commun., 2010,11:1137-1142

    12. [12]

      [12]JIANG Li-Long(江莉龙), Ma Yong-De(马永德), CAO Yan-Ning(曹彦宁), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(6):1157-1164

    13. [13]

      [13]JIANG Li-Long(江莉龙), Ma Yong-De(马永德), CAO Yan-Ning(曹彦宁), et al. Acta Phys.-Chin. Sin.(Wuli Huaxue Xuebao), 2012,28(03):674-680

    14. [14]

      [14]Faungnawakij K, Shimoda N, Fukunaga T, et al. Appl. Catal., B, 2009,92:341-350

    15. [15]

      [15]Yang X M, Wei Y, Su Y L, et al. Fuel Process. Technol., 2010,91:1168-1173

    16. [16]

      [16]Gingasu D, Mindru I, Patron L, et al. J. Alloys Compd, 2008,460:627-631

    17. [17]

      [17]Ristic M, Hannoyer B, Popovic S, et al. Mater. Sci. Eng., B, 2000,77:73-82

    18. [18]

      [18]Khan A, Smirniotis P G. J. Mol. Catal. A: Chem., 2008,280: 43-51

    19. [19]

      [19]Estrella M, Barrio L, Zhou G, et al. J. Phys. Chem. C, 2009, 113:14411-14417

    20. [20]

      [20]Mahajan R P, Patankar K K, Kothale M B, et al. Bull. Mater. Sci., 2000,23:273-279

    21. [21]

      [21]Liu Y C, Fu Y P. Ceram. Int., 2010,36:1597-1601

    22. [22]

      [22]ZHANG Ping(张平), YU Bo(于波), ZHANG Lei(张磊). Sci. China B: Chem.(Zhonguo Kexue B),2008,38(7):624-630

    23. [23]

      [23]Parmigiani F, Pacchioni G, Illas F, et al. J. Electron Spectrosc. Relat. Phenom., 1992,59:255-269

    24. [24]

      [24]Jolley J G, Geesey G, Haukins M R, et al. Appl. Surf. Sci., 1989,37:469-480

    25. [25]

      [25]Nakamura T, Tomizuka H, Takahashi M, et al. J. Surf. Sci. Soc.Jpn., 1995,16:515-521

    26. [26]

      [26]McIntyre N S, Cook M G. Anal. Chem., 1975,47:2208-2213

    27. [27]

      [27]Sing K S W, Everett D H, Haul R A W, et al. Pure Appl. Chem., 1985,57:603-619

    28. [28]

      [28]Venugopal A, Aluha J, Scurrell M S, et al. Appl. Catal. A, 2003,45:149-158

    29. [29]

      [29]Jozwiak W K, Kaczmarek E, Maniecki T P, et al. Appl. Catal. A, 2007,326:17-27

    30. [30]

      [30]Delahay G, Coq B, Broussous L. Appl. Catal. B, 1997,12: 49-59

    31. [31]

      [31]YE Qing(叶青), YAN Li-Na(闫立娜), HUO Fei-Fei(霍飞飞), et al. Acta Chimica Sinica(Huaxue Xuebao), 2011,69(13): 1524-1532

    32. [32]

      [32]Charles Kittel, Ryosei Uno(宇野良淸)． Introduction to Solid State Physics(固体物理学入门)． Japan: Maruzen, 1988.

    33. [33]

      [33]Lohitharn N, Goodwin J G, Lotero E. J. Catal., 2008,255: 104-113

    34. [34]

      [34]Lee H C, Kim D H. Catal. Today, 2008,132:109-113

    35. [35]

      [35]Pan Z Y, Dong M H, Meng X K, et al. Chem. Eng. Sci., 2007,62(10):2712-2715

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