Citation: QIU Wen-Ge, DENG Fang, LIU Hu-Bing, ZI Xue-Hong, ZHANG Gui-Zhen, HE Hong, LI Jian-Rong. A sqc422-Type Coordination Polymer Based on Flexible Tetracarboxylate and 4,4'-Bipyridine Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2021-2026. doi: 10.3969/j.issn.1001-4861.2013.00.335 shu

A sqc422-Type Coordination Polymer Based on Flexible Tetracarboxylate and 4,4'-Bipyridine Ligands

1.
Department of Chemistry and Chemical Engineering, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China

Received Date: 4 January 2013
Available Online: 27 May 2013
Fund Project: 国家自然科学基金(No.21007002)资助项目。 (No.21007002)

By using hydrothermal method, a cobalt complex, namely, [Co₂(L)(Bipy)₂]_n, (1), was synthesized based on flexible 1,3-bis[3,5-(dicarboxylate)phenoxy]-2-hydroxypropane(H4L) and 4,4'-bipyridine(Bipy). The complex 1 was characterized by infra-red spectrum (IR), UV-Vis spectrum, thermo-gravimetric analysis (TGA), single crystal X-ray diffraction, powder X-ray diffraction and elemental analysis. Complex 1 crystalizes in monoclinic system, space group C2/c. In complex 1, two six-coordinated cobalt atoms were connected by two bidentate carboxylic groups, forming an octahedral dimetallic cluster, which can be considered as a 6-connected node to connect four L ligand molecules and two other dimetallic clusters. The flexible tetracarboxylate ligand L can be considered as a tetrahedral 4-connected node to connect four dimetallic clusters. The two parallel Bipy molecules bridging two dimetallic clusters are transformed into edge during simplification. Thus, the framework of 1 features a sqc422 net. CCDC: 947285.
- 1,3-bis[3,5-(dicarboxylate)phenoxy]-2-hydroxypropane; 4,4'-bipyridine; cobalt complex; metal-organic frameworks; sqc422 net; π-π stacking interaction
1. [1]
  [1] Bastin L, Barcia P S, Hurtado E J, et al. J. Phys. Chem. C, 2008,112:1575-1581 [2] Pan L, Olson D H, Ciemnolonski L R, et al. Angew. Chem. Int. Ed., 2006,45:616-619 [3] Ma S, Sun D, Simmons J M, et al. J. Am. Chem. Soc., 2008, 130:1012-1016 [4] Rowsell J L C, Millward A R, Park K S, et al. J. Am. Chem. Soc., 2004,126:5666-5667 [5] Seo J S, Whang D, Lee H, et al. Nature, 2000,404:982-986 [6] Ma L, Abney C, Lin W. Chem. Soc. Rev., 2009,38:1248- 1256 [7] Horcajada P, Serre C, Vallet-Regi M, et al. Angew. Chem. Int. Ed., 2006,45:5974-5978 [8] Moulton B, Zaworotko M J. Chem. Rev., 2001,101:1629- 1658 [9] Bourne S A, Lu J, Mondal A, et al. Angew. Chem. Int. Ed., 2001,40:2111-2113 [10]Moulton B, Lu J, Mondal A, et al. Chem. Commun., 2001: 863-864 [11]Eddaoudi M, Kim J, Wachter J B, et al. J. Am. Chem. Soc., 2001,123:4368-4369 [12]Ke Y, Collins D J, Zhou H C. Inorg. Chem., 2005,44:4154- 4156 [13]Lin X, Telepeni I, Blake A J, et al. J. Am. Chem. Soc., 2009,131:2159-2171 [14]Perman J A, Cairns A J, Wojtas L, et al. CrystEngComm, 2011,11:3130-3133 [15]Zhao D, Yuan D, Sun D, et al. J. Am. Chem. Soc., 2009, 131:9186-9188 [16]Yuan D, Zhao D, Sun D, et al. Angew. Chem. Int. Ed., 2010,49:5357-5361 [17]Yan Y, Telepeni I, Yang S, et al. J. Am. Chem. Soc., 2010, 132:4092-4094 [18]Perry IV J J, Kravtsov V C, McManus G J, et al. J. Am. Chem. Soc., 2007,129:10076-10077 [19]Wang X S, Ma S, Forster P M, et al. Angew. Chem. Int. Ed., 2008,47:7263-7266 [20]Qiu W G, Perman J A, Wojtas L, et al. Chem. Comm., 2010,46:8734-8736 [21]Li C Q, Qiu W G, Shi W, et al. CrystEngComm, 2012,14: 1929-1932 [22]Piantadosi C, Hall I H, Wyrick S D, et al. J. Med. Chem., 1976,19:222-229 [23]Gupta S, Pandey G, Rahuja N, et al. Bioorg. Med. Chem. Lett., 2010,20:5732-5734 [24]Sluis P van der, Spek A L. Acta Cryst., 1990,A46:194-201 [25]Pan L, Ching N, Huang X, et al. Inorg. Chem., 2000,39: 5333-5340 [26]SHI Zhong-Feng(史忠丰), JIN Jing(金晶), LI Lei(李雷), et al. Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2009,25 (10):2011-2019 [27]Taddei M, Costantino F, Vivani R, et al. Cryst. Growth Des., 2012,12:2327-2335 [28]Prior T J, Bradshaw D, Teat S J, et al. Chem. Commun., 2003:500-501 [29]Choi E Y, Kwon Y U. Inorg. Chem., 2005,44:538-545 [30]Spek A L. J. Appl. Crystallogr., 2003,36:7-13 [31]Blatov V A, Shevchenko A P. TOPOS, V4.0 Professional, Samara State University, Samara, Russia, 2006. [32]Yang W T, Guo M, Yi F Y, et al. Cryst. Growth Des., 2012, 12:5529-5534 [33]For More Information about sqc422 Net, see:http://epinet. anu.edu.au/sqc422 [34]Deacon G B, Phillips R J. Coord. Chem. Rev., 1980,33(3): 227-250 [35]Shen C J, Sheng T L, Zhu Q L, et al. CrystEngComm, 2012, 14:3189-3198 [36]GUO Jin-Yu(郭金玉), ZHANG Jian-Guo(张建国), ZHANG Tong-Lai(张同来). Acta Chim. Sin.(Huaxue Xuebao), 2006, 64(16):1693-1699
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沈阳化工大学材料科学与工程学院沈阳 110142